安徽理工大学学报(自然科学版)2024,Vol.44Issue(5) :85-90.DOI:10.3969/j.issn.1672-1098.2024.05.011

改性石墨相氮化碳结构与性能的影响

Effect of Modified Graphite Phase Carbon Nitride on the Structure and Properties

于清波 王猛 徐子涉 刘凡
安徽理工大学学报(自然科学版)2024,Vol.44Issue(5) :85-90.DOI:10.3969/j.issn.1672-1098.2024.05.011

改性石墨相氮化碳结构与性能的影响

Effect of Modified Graphite Phase Carbon Nitride on the Structure and Properties

于清波 1王猛 1徐子涉 1刘凡1
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作者信息

  • 1. 安徽理工大学材料科学与工程学院,安徽 淮南 232001
  • 折叠

摘要

目的 为了提高石墨相氮化碳的光催化降解污染物的能力.方法 通过水热的方法用间苯二甲酸对双氰胺进行改性,研究不同间苯二甲酸添加量对降解性能的影响.结果 结果表明,经过间苯二甲酸改性的石墨相氮化碳光催化效率相较于纯石墨相氮化碳有明显提高,其降解速率常数为0.0736min-1,为石墨相氮化碳的1.68倍.间苯二甲酸的添加会与双氰胺之间形成相互作用,这种相互作用会抑制和促进部分晶面的生长,并在煅烧过程中使三-s-三嗪环结构增多,使改性石墨相氮化碳结构更加松散,层间距增大,更多碳插入片层中.致使的瞬态光电流更大,转移电子更快,从而最终光催化性能得到提高.结论 研究结果对于增强光催化降解污染物提供了另一种思路.

Abstract

Objective In order to improve the photocatalytic degradation ability of graphite phase carbon nitride.Methods Dicyandiamide was modified with isophthalic acid withthe hydrothermal method,and the effect of differ-ent dosage of isophthalic acid on degradation performance was studied.Results The photocatalytic efficiency of carbon nitride modified by isophnic acid was significantly improved compared with that of pure carbon nitride,and its degradation rate constant was 0.0736min-1,which was 1.68 times that of carbon nitride.The addition of isophanic acid wasableto form an interaction with dicandiamide,which inhibited and promoted the growth of some crystal faces,increasing the tri-S-triazine ring structure during calcination,whichmade the modified graphite phase carbon nitride structure looser,increased the layer spacing and inserted more carbon into the lamellae.Therefore,the transient photocurrent of the modified graphite phase carbon nitride was larger and the electron transfer was faster,improving the photocatalytic performance.Conclusion The results provide another way to en-hance photocatalytic degradation of pollutants.

关键词

间苯二甲酸/石墨相氮化碳/光催化

Key words

isophthalic acid/graphitic carbon nitride/photocatalysis

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出版年

2024
安徽理工大学学报(自然科学版)
安徽理工大学

安徽理工大学学报(自然科学版)

影响因子:0.331
ISSN:1672-1098
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