河南化工2025,Vol.42Issue(1) :40-43.

铁基生物炭活化过一硫酸盐降解水中的阿特拉津

The Removal of Atrazine from Water by Iron-Based Biochar Activated Persulfate

王廷文 唐晓洁 李长春 武倩倩 程浩然 黄国富
河南化工2025,Vol.42Issue(1) :40-43.

铁基生物炭活化过一硫酸盐降解水中的阿特拉津

The Removal of Atrazine from Water by Iron-Based Biochar Activated Persulfate

王廷文 1唐晓洁 2李长春 2武倩倩 2程浩然 2黄国富2
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作者信息

  • 1. 山东北方三潍环保科技有限公司,山东 潍坊 261202
  • 2. 潍坊科技学院 化工与环境学院,山东 潍坊 262700
  • 折叠

摘要

水体中有机农药阿特拉津(Atrazine,ATZ)的污染问题受到了广泛关注.采用高温碳热还原法制备铁基生物炭材料(Fe/BC),并活化过一硫酸盐(PMS)降解水中的有机农药ATZ.表征结果表明,Fe/BC800 材料(反应温度800℃)为不规则结构,表面存在大量的零价铁(Fe0)颗粒.批式实验表明,与Fe/BC700和Fe/BC900相比,Fe/BC800能更有效活化PMS去除ATZ;适量的PMS浓度,有利于ATZ的去除;酸性及中性条件下,ATZ的去除效果好,强碱性环境下,ATZ的去除受抑制,为高级氧化技术的发展和ATZ的高效去除提供了理论依据.

Abstract

The contamination problem of organic pesticide atrazine(ATZ)in water has received much at-tention.An iron-based biochar material(Fe/BC)is prepared by high-temperature carbothermal reduc-tion method and activated permonosulfate(PMS)to degrade ATZ in water.Characterization results show that the Fe/BC800 material(reaction temperature of 800℃)is irregular in structure with a large number of zero-valent iron(Fe0)particles on the surface.Batch experiments show that Fe/BC800 could activate PMS more effectively to remove ATZ compared with Fe/BC700 and Fe/BC900,moderate PMS concentration is favourable for the removal of ATZ,the removal of ATZ is favourable under acidic and neutral condi-tions,and is inhibited in a strongly alkaline environment.It provides a theoretical basis for the develop-ment of advanced oxidation technology and the efficient removal of ATZ.

关键词

生物炭/零价铁/过一硫酸盐/阿特拉津/高级氧化技术

Key words

biochar/zero-valent iron/peroxymonosulface/atrazine/advanced oxidation technology

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出版年

2025
河南化工
河南省化工研究所

河南化工

影响因子:0.263
ISSN:1003-3467
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