首页|铁基生物炭活化过一硫酸盐降解水中的阿特拉津

铁基生物炭活化过一硫酸盐降解水中的阿特拉津

扫码查看
水体中有机农药阿特拉津(Atrazine,ATZ)的污染问题受到了广泛关注.采用高温碳热还原法制备铁基生物炭材料(Fe/BC),并活化过一硫酸盐(PMS)降解水中的有机农药ATZ.表征结果表明,Fe/BC800 材料(反应温度800℃)为不规则结构,表面存在大量的零价铁(Fe0)颗粒.批式实验表明,与Fe/BC700和Fe/BC900相比,Fe/BC800能更有效活化PMS去除ATZ;适量的PMS浓度,有利于ATZ的去除;酸性及中性条件下,ATZ的去除效果好,强碱性环境下,ATZ的去除受抑制,为高级氧化技术的发展和ATZ的高效去除提供了理论依据.
The Removal of Atrazine from Water by Iron-Based Biochar Activated Persulfate
The contamination problem of organic pesticide atrazine(ATZ)in water has received much at-tention.An iron-based biochar material(Fe/BC)is prepared by high-temperature carbothermal reduc-tion method and activated permonosulfate(PMS)to degrade ATZ in water.Characterization results show that the Fe/BC800 material(reaction temperature of 800℃)is irregular in structure with a large number of zero-valent iron(Fe0)particles on the surface.Batch experiments show that Fe/BC800 could activate PMS more effectively to remove ATZ compared with Fe/BC700 and Fe/BC900,moderate PMS concentration is favourable for the removal of ATZ,the removal of ATZ is favourable under acidic and neutral condi-tions,and is inhibited in a strongly alkaline environment.It provides a theoretical basis for the develop-ment of advanced oxidation technology and the efficient removal of ATZ.

biocharzero-valent ironperoxymonosulfaceatrazineadvanced oxidation technology

王廷文、唐晓洁、李长春、武倩倩、程浩然、黄国富

展开 >

山东北方三潍环保科技有限公司,山东 潍坊 261202

潍坊科技学院 化工与环境学院,山东 潍坊 262700

生物炭 零价铁 过一硫酸盐 阿特拉津 高级氧化技术

2025

河南化工
河南省化工研究所

河南化工

影响因子:0.263
ISSN:1003-3467
年,卷(期):2025.42(1)