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土壤中无机氮检测方法研究进展

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土壤中无机氮含量的检测是了解土壤氮迁移、精准把控氮肥施用量、有效防治土壤氮素过量的首要前提.本文对现行国内外土壤中无机氮的标准分析方法的原理、特性及优缺点进行了归纳和总结.结果发现,现行标准中使用的方法基本为分光光度法和凯式法.现行手工分析法操作步骤多、耗时长,难以满足批量土壤样品快速分析测试的要求.自动仪器分析法反应复杂、易受干扰,直接影响测定结果的准确性.此外,在基于同种原理的前提下,现行标准在前处理方法及检测条件等方面存在众多不统一,导致所得数据不具有可比性.通过综合比较后提出,气相分子吸收光谱法在方法性能、检测效率及仪器成本等方面具有明显优势,必将成为今后各级标准制修订的首选方法.
An Overview of Research on Inorganic Nitrogen Detection Methods in Soil
Concentration of inorganic nitrogen in soil is the first prerequisite for understanding soil nitrogen migration in time,controlling nitrogen application accurately and preventing soil nitrogen pollution effectively.In this paper,the principles,characteristics,advantages and disadvantages of the existing foreign and domestic standard analytical methods for inorganic nitrogen in soil were summarized.It was found that the methods used in the current standards are basically spectrophotometric and Kjeldahl methods.Manual analytical methods have the disadvantages of many operation steps and long time-consuming,which can hardly satisfy the requirements of rapid analysis and testing of batch soil samples.Automated instrument analysis methods have the drawbacks of complex reactions and susceptibility to interference,which directly affect the accuracy of measurement results.In addition,under the premise of the same principle,there are many inconsistencies in the pretreatment methods and detection conditions of the existing standards,which lead to the non-comparability of the data obtained.After comprehensive comparison with the methods used in various research reports at present,it is proposed that Gas-Phase Molecular Absorption Spectrometry has obvious advantages in terms of method performance,detection efficiency,and instrument cost,and will definitely become the preferred method for standard formulation and revision in the future.

soilinorganic nitrogendetection methodsgas-phase molecular absorption spectroscopy

彭晓、杨萌、王晓雯、刘进阳、周艺蓉

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辽宁省大连生态环境监测中心,辽宁 大连 116023

大连市生态环境事务服务中心,辽宁 大连 116023

土壤 无机氮 检测方法 气相分子吸收光谱

辽宁省生态环境厅生态环境科研计划(2021)

辽环综函[2020]521号

2024

湖南生态科学学报
湖南环境生物职业技术学院

湖南生态科学学报

影响因子:0.341
ISSN:2095-7300
年,卷(期):2024.11(1)
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