首页|基于"混凝脱色-生物降解"组合工艺的水性油墨废水处理研究

基于"混凝脱色-生物降解"组合工艺的水性油墨废水处理研究

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[目的]由于水性油墨废水色度高、化学需氧量高且难生物降解,需对其脱色及生物处理工艺进一步进行研究.针对某水性油墨废水(色度为1 000倍,pH值为6.5~7.5,COD为1 609 mg/L)使用硫酸亚铁、壳聚糖分别作为混凝剂和助凝剂对其进行脱色处理,同时为解决传统铁盐混凝剂使用后出现的溶液"泛黄"问题提供解决方法.[方法]在混凝剂投加量为1 000 mg/L、助凝剂投加量为0.7 mg/L、pH值为8.0左右,总反应时间为8.5 min条件下,使用有效氯含量(以Cl计)达到6%,并用7 mL/L的次氯酸钠溶液对试验体系进行优化.[结果]油墨废水脱色率可达98%左右,在保证脱色效果的前提下采用优化方法可将混凝剂投加量降至500 mg/L,且能有效解决"泛黄"问题.[结论]针对脱色后无法去除的COD(725 mg/L左右),通过"水解酸化+好氧"生物处理可将COD降至103 mg/L,符合企业排污许可证的排放标准,提出的解决常见的铁盐混凝剂"泛黄"问题的思路,具有一定的实际应用价值.
Research on Water-Based Ink Wastewater Treatment Based on "Coagulation Decolorization-Biodegradation" Combined Process
[Purposes]Due to the high chroma,high chemical oxygen demand and difficult biodegradation of water-based ink wastewater,its decolorization and biological treatment process need to be further studied.In this paper,pH:6.5-7.5,COD:1 609 mg/L),using ferrous sulphate,chitosan as a coagulant and coagulant aid,was done to address the issue of the solution"yellowing"after using a traditional iron salt coagulant.[Methods]The experimental system was optimized with 7 mL/L of sodium hypochlorite solu-tion,under the condition of 1 000 mg/L of coagulant,0.7 mg/L of coagulant aid,a pH of about 8.0,and an 8.5-minute total reaction time,and the content of available chlorine(Cl)is 6%.[Findings]The decol-orization rate of the ink wastewater can reach 98%,and the coagulant dosage can be reduced to 500 mg/L under the premise of guaranteeing the decolorization effect by using the optimised method,which can effec-tively solve the problem of"yellowing".[Conclusions]The COD(about 725 mg/L),which cannot be removed after decolorization,can be reduced to 103 mg/L by"hydrolysis acidification+aerobic"biological treatment,which is in line with the discharge standard of the enterprise's discharge permit,and the idea of solving the common"yellowing"problem of iron salt coagulant was successfully put forward,which is economical,reliable and has certain practical application value.

water-based ink wastewatercoagulationdecolorizationbiodegradationcombined process

陈莉杰、王梦晗、李晓敏、郭聪聪、卢峥、王艺涵、吴朕君

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河南工业大学环境工程学院,河南 郑州 450001

水性油墨废水 混凝 脱色 生物降解 组合工艺

河南省科技厅自然科学基金项目-青年科学基金项目郑州市科技局自然科学项目-协同创新专项河南省博士后科研项目

20230041010722ZZRDZX12202001050

2024

河南科技
河南省科学技术信息研究院

河南科技

影响因子:0.615
ISSN:1003-5168
年,卷(期):2024.51(2)
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