河南科技2024,Vol.51Issue(19) :78-82.DOI:10.19968/j.cnki.hnkj.1003-5168.2024.19.016

Yb3+,Eu3+共掺杂BaSiO3上/下转换发光与能量传递研究

Study on Yb3+,Eu3+Co-doped BaSiO3 Up/Down Conversion Luminescence and Energy Transfer

纳治国 朱慧敏 吐尔逊·艾迪力比克 巴合提古丽·阿斯里别克
河南科技2024,Vol.51Issue(19) :78-82.DOI:10.19968/j.cnki.hnkj.1003-5168.2024.19.016

Yb3+,Eu3+共掺杂BaSiO3上/下转换发光与能量传递研究

Study on Yb3+,Eu3+Co-doped BaSiO3 Up/Down Conversion Luminescence and Energy Transfer

纳治国 1朱慧敏 1吐尔逊·艾迪力比克 1巴合提古丽·阿斯里别克1
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作者信息

  • 1. 伊犁师范大学,新疆 伊宁 835000
  • 折叠

摘要

[目的]研究BaSiO3掺杂Yb3+,Eu3+的上转换发光特性,为开发荧光防伪技术提供试验基础.[方法]采用高温固相法合成了一系列BaSiO3:Yb3+,Eu3+荧光粉,利用X射线衍射仪(XRD)、稳态光谱仪等设备对样品的物相结构和发光特性进行表征.[结果]XRD结果表明,Yb3+离子、Eu3+离子成功进入硅酸钡晶格且对基质晶格没有产生影响.980 nm激发下,BaSiO3:1%Yb3荧光粉发射峰位于483 nm,这归因于Yb3+二聚体合作发光.进一步用980 nm激光器激发BaSiO₃:Yb3+,Eu3+荧光粉,同时出现了483 nm Yb3+二聚体的发射光谱和575~705 nm处Eu3+离子的发射光谱,表明Yb3+二聚体通过上转换合作发光将能量传递给Eu3+离子,此时的色坐标为(0.498 9,0.350 5),色温为1 840 k.[结论]该材料的研究在防伪、太阳能电池和照明等方面具有潜在应用价值.

Abstract

[Purposes]The up-conversion luminescence properties of BaSiO₃ doped Yb3+,Eu3+were studied,which provided experimental basis for the development of fluorescent anti-counterfeiting tech-nology.[Methods]A series of BaSiO₃:Yb3+,Eu3+phosphors were synthesized by high-temperature solid-phase method.The physical structure and luminescence properties of the samples were characterized us-ing X-ray diffractometer(XRD)and steady state spectrometer.[Findings]The XRD results showed that Yb3+ions and Eu3+ions successfully entered the barium silicate lattice and had no effect on the matrix lat-tice.980 nm excitation showed that the emission peak of BaSiO₃:1%Yb3 phosphor was located at 483 nm,which was attributed to the cooperative luminescence of Yb3+dimer.Further excitation of BaSiO₃:Yb3+,Eu3+phosphor with a 980 nm laser resulted in simultaneous emission spectra of the Yb3+dimer at 483 nm and Eu3+ions at 575~705 nm,suggesting that the Yb3+dimer transfers its energy to the Eu3+ions through upconversion co-luminescence.The color coordinates are(0.498 9,0.350 5),and the color temperature is 1 840 k.[Conclusions]Therefore,the study of this material has potential applications in anti-counterfeiting,solar cells and lighting.

关键词

稀土掺杂/荧光光谱/上转换发光/合作发光/色坐标

Key words

rare earth doped/fluorescence spectroscopy/upconversion luminescence/cooperative lumi-nescence/color coordinates

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出版年

2024
河南科技
河南省科学技术信息研究院

河南科技

影响因子:0.615
ISSN:1003-5168
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