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非热等离子体协同催化还原脱硝的研究进展

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非热等离子体(NTP)协同催化还原脱硝技术是一种新兴的烟气处理方法,它结合了NTP和选择性催化还原(SCR)技术的优势,通过在低温条件下产生等离子体,利用高能电子、离子、自由基等活性粒子与氮氧化物(NOx)发生反应,实现脱硝.本综述深入探讨了NTP-SCR技术的研究进展,包括等离子体的产生和基本原理、催化剂的改进、反应机制、数值模拟研究,以及该技术在空气净化领域的应用潜力和面临的挑战.NTP-SCR在低温下表现出高效的脱硝能力,减少了有害副产物的生成,并降低了能耗.NTP处理可以增强催化剂性能,尤其是催化剂在低温和恶劣烟气环境下的活性和耐久性.反应机理研究表明,NTP能够激活催化剂表面,促进NOx的还原过程.同时,数值模拟的应用为等离子体反应器的设计和操作提供了理论指导.尽管NTP-SCR技术具有显著的潜力,但仍面临一些挑战,包括长期稳定性、产物选择性控制,以及如何将实验室研究成果转化为工业应用.未来的研究将集中在开发更高效、更稳定的NTP协同催化剂,优化工艺参数,以及深入探索等离子体与催化剂之间的协同作用机制.
Review on Non-thermal Plasma Synergistic Catalytic Reduction of NOx
Non-thermal plasma(NTP)synergistic catalytic reduction denitrification technology is an emerging flue gas treatment method that combines the advantages of NTP and selective catalytic reduction(SCR)technology.It generates plasma at low temperatures,using high-energy electrons,ions,and free radicals to react with nitrogen oxides(NOx)to achieve denitrification.This review delves into the research progress of NTP-SCR technology,including the generation and fundamental principles of plasma,catalyst improvement,reaction mechanisms,numerical simulation studies,as well as the application potential and challenges of this technology in the field of air purification.NTP-SCR demonstrates high denitrification efficiency at low temperatures,reduces the generation of harmful by-products,and lowers energy consumption.NTP treatment can enhance catalyst performance,especially the activity and durability of catalysts in low-temperature and harsh flue gas environments.Mechanism studies indicate that NTP can activate the catalyst surface and promote the reduction process of NOx.Meanwhile,the application of numerical simulation provides theoretical guidance for the design and operation of plasma reactors.Although NTP-SCR technology has significant potential,it still faces some challenges,including long-term stability,control of product selectivity,and how to translate laboratory research results into industrial applications.Future research will focus on developing more efficient and stable NTP synergistic catalysts,optimizing process parameters,and further exploring the synergistic action mechanism between plasma and catalysts.

non-thermal plasmareduction of NOxsynergistic catalyticair purificationnitrogen oxide

赵玮璇

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河南省科学院光资源与环境研究院,郑州 450000

非热等离子体 还原脱硝 协同催化 空气净化 氮氧化物

2025

河南科学
河南省科学院

河南科学

影响因子:0.391
ISSN:1004-3918
年,卷(期):2025.43(1)