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两性聚合物P(AM-AA-AN)-g-TETA的合成及脱色性能研究

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单体丙烯酰胺(AM)、丙烯酸(AA)、丙烯腈(AN)在水溶液中无规共聚,然后以三乙烯四胺(TETA)和氯化铵作为改性剂,制备了两性聚合物P(AM-AA-AN)-g-TETA脱色剂.通过红外光谱(FT-IR)和凝胶渗透色谱(GPC)对两性聚合物的官能团结构和分子量及分布进行了表征.以活性红和活性黄为模拟染料,对两性聚合物的投料量、水pH以及氯化钠浓度对脱色效果的影响进行了研究.所制备的两性聚合物的投料量在200 mg/L时,脱色率就能达到80%以上;在中性及酸性条件下脱色效果较好,碱性条件脱色效果降低;随着氯化钠浓度的提高,脱色效果有降低的趋势.本研究合成的与市售的脱色剂相比,对活性黄的脱色效果明显提高,具有一定的应用前景.
Synthesis and Decolorization Performance of Amphiphilic Polymer P(AM-AA-AN)-g-TETA
Amphoteric polymer P(AM-AA-AN)-g-TETA decolorizer was synthesized by random copolymerization of acrylamide(AM),acrylic acid(AA)and acrylonitrile(AN)in aqueous solution with triethylenetetramine(TETA)and ammonium chloride as modifiers.The functional group structure,molecular weight and distribution of the amphoteric polymer were characterized using FT-IR and GPC.The effects of amphoteric polymer dosage,water pH and sodium chloride concentration on decolorization were studied,using reactive red and reactive yellow as simulated dyes.When the dosage of the amphoteric polymer is 200 mg/L,the decolorization rate exceeds 80%.The decolorization performance is better under neutral and acidic conditions,but lower under alkaline conditions.With the increase of sodium chloride concentration,the decolorization effect tends to decrease.Compared with the decolorizing agent on the market,the decolorizing effect of active yellow is significantly improved,and it has a certain application prospect.

amphoteric polymerreactive dyesdecolorizing flocculantsolution polymerization

宋跃、谷雨、王连杰、靳瑞文、张奇、王冰磊、李中贤

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河南省科学院高新技术研究中心,郑州 450000

生态环境部黄河流域生态环境监督管理局黄河生态环境科学研究所,郑州 450000

两性聚合物 活性染料 脱色絮凝剂 溶液聚合

2025

河南科学
河南省科学院

河南科学

影响因子:0.391
ISSN:1004-3918
年,卷(期):2025.43(1)