华南师范大学学报(自然科学版)2024,Vol.56Issue(4) :54-59.DOI:10.6054/j.jscnun.2024050

外延Ba0.6Sr0.4TiO3铁电薄膜的制备及介电储能性能

Preparation of Epitaxial Ba0.6Sr0.4TiO3 Ferroelectric Thin Film and Its Dielectric Energy Storage Performance

冀思雨 樊晓雨 曹以琳 高珺怡 杨帆 宋建民 张宪贵
华南师范大学学报(自然科学版)2024,Vol.56Issue(4) :54-59.DOI:10.6054/j.jscnun.2024050

外延Ba0.6Sr0.4TiO3铁电薄膜的制备及介电储能性能

Preparation of Epitaxial Ba0.6Sr0.4TiO3 Ferroelectric Thin Film and Its Dielectric Energy Storage Performance

冀思雨 1樊晓雨 1曹以琳 1高珺怡 1杨帆 1宋建民 1张宪贵2
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作者信息

  • 1. 河北农业大学理学院,保定 071002
  • 2. 河北农业大学理学院,保定 071002;河北农业大学渤海学院,沧州 061100
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摘要

利用偏轴磁控溅射技术,在(001)LaAlO3单晶衬底上构架了 Pt/Ba0.6Sr0.4TiO3(BST)/La0.5Sr0.5CoO3(LSCO)铁电电容器,研究了 BST薄膜的结构与形貌、介电、漏电和储能性能.结果表明:BST薄膜为外延结构生长,表面光滑致密,其均方根粗糙度为1.228 nm.Pt/BST/LSCO电容器具有优异的介电性能,100 kHz频率下调谐率和最大损耗分别为73.73%和0.078,漏电流密度较低(10-6 A/cm2量级).此外,BST薄膜展现了良好的储能特性及温度稳定性,在10 kHz频率和2 000 kV/cm外加场强下,其室温总储能密度、有效储能密度和储能效率分别为27.01 J/cm3、16.03 J/cm3和59.4%;在1 200 kV/cm外加场强下,温度为105 ℃时储能效率可高达72.2%,这主要归因于较高温度促进了离子的热运动,从而有效提升了储能效率.

Abstract

A Pt/Ba0.6Sr0.4TiO3(BST)/La0.5Sr0.5CoO3(LSCO)ferroelectric capacitor was fabricated on(001)LaAlO3 single crystal substrate using off-axis magnetron sputtering technology.The structure,morphology,and va-rious properties,including dielectric,leakage,and energy storage performance of the BST film,were investigated in detail.The results indicate that the BST thin film is grown epitaxially and has a smooth and dense surface with a root mean square roughness of 1.228 nm.The Pt/BST/LSCO capacitor exhibits excellent dielectric properties with tunability and maximum loss of 73.73%and 0.078 at a frequency of 100 kHz,respectively,as well as lower leak-age current densities(on the order of 10-6 A/cm2).In addition,the BST thin film demonstrates favorable energy storage performance and temperature stability.At a frequency of 10 kHz and an applied electric field of 2 000 kV/cm,the total energy storage density,effective energy storage density,and energy storage efficiency at room temper-ature are 27.01 J/cm3,16.03 J/cm3,and 59.4%,respectively.With increasing temperature up to 105 ℃,the en-ergy storage efficiency can reach as high as 72.2%with an applied electric field of 1 200 kV/cm,which can be at-tributed to the higher temperature promoting the thermal movement of ions,thereby effectively improving the energy storage efficiency.

关键词

Ba0.6Sr0.4TiO3/铁电薄膜/介电/储能

Key words

Ba0.6Sr0.4TiO3/ferroelectric thin film/dielectric/energy storage

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基金项目

教育部合作与教研专项(231102070271447)

河北省高校基本科学研究项目(KY2024011)

河北省高校基本科学研究项目(KY2023028)

河北农业大学创新训练项目(2024306)

河北农业大学创新训练项目(2024314)

出版年

2024
华南师范大学学报(自然科学版)
华南师范大学

华南师范大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.413
ISSN:1000-5463
参考文献量2
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