首页|基于混凝土表面SO42-浓度时变的扩散模型预测研究

基于混凝土表面SO42-浓度时变的扩散模型预测研究

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为探究混凝土在硫酸盐侵蚀下的腐蚀破坏情况,通过考虑混凝土表面SO42-浓度时变规律,改进现有的扩散-反应方程组,结合水泥水化、腐蚀产物填充和损伤度函数建立了硫酸盐侵蚀下混凝土扩散模型.采用Comsol Multiphysics软件模拟在不同硫酸盐浓度侵蚀下,不同侵蚀龄期内混凝土各截面SO42-浓度,并将模型计算值与实测值进行对比.结果表明:在硫酸盐浓度为 5%和10%的侵蚀条件下,考虑混凝土表面SO42-浓度时变过程的模型计算值和实测值的最大误差分别为 17.46%及 19.69%,验证了模型的合理性与适用性.最后通过建立的SO42-侵蚀混凝土最大深度预测模型,发现硫酸盐侵蚀混凝土的最大侵蚀深度在侵蚀前期快速增加,随着侵蚀龄期的延长而逐渐变缓,以期为混凝土的耐久性评估提供参考.
Research on diffusion model prediction based on time-varying sulfate ion concentration on concrete surface
To explore the corrosion damage of concrete under sulfate attack.By considering the time-varying law of the concentration of SO42-on the concrete surface,improving the existing diffusion-reaction equations,combining cement hydration,corrosion product filling and damage degree functions,a concrete damage model under sulfate erosion is established.Comsol Multiphysics was used to simulate the SO42-concentration of each cross-section of concrete under different sulfate concentrations and different erosion ages,and the calculated values of the model were compared with the measured values.The results show that under the erosion conditions of sulfate concentration of 5%and 10%,the maximum error between the calculated value and the measured value considering the time-varying process of SO42-concentration on the concrete surface is 17.46%and 19.69%,respectively.Through the established prediction model of the maximum depth of SO42-eroded concrete,it is found that the maximum erosion depth of sulfate eroded concrete increases rapidly in the early stage of erosion,and gradually slows down with the extension of erosion age,so as to provide reference for the durability evaluation of concrete.

concretesulfate erosiontime-varying surface ion concentrationdepth prediction

任青阳、任小坤、靳红华

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重庆交通大学山区桥梁及隧道工程国家重点实验室,重庆 400074

重庆交通大学土木工程学院,重庆 400074

混凝土 硫酸盐侵蚀 表面离子浓度时变 深度预测

国家自然科学基金重庆市自然科学基金重点项目重庆市高校创新研究群体首批重庆英才创新领军人才重庆市研究生科研创新项目

41472262cstc2020jcyjzdxmX0012CXQT19021CQYC201903026CYB21210

2024

混凝土
中国建筑东北设计研究院有限公司

混凝土

CSTPCD北大核心
影响因子:0.844
ISSN:1002-3550
年,卷(期):2024.(1)
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