混凝土2024,Issue(1) :116-119,123.DOI:10.3969/j.issn.1002-3550.2024.01.022

木质素磺酸钙对模拟混凝土孔隙腐蚀液中碳钢阻锈作用

Effect of calcium lignosulfonate on rust resistance of carbon steel in simulated concrete pore solution

周钰鑫 季涛 靳丁帅男 施佳汇 王海洲 周鸣 牛龙龙 张士萍
混凝土2024,Issue(1) :116-119,123.DOI:10.3969/j.issn.1002-3550.2024.01.022

木质素磺酸钙对模拟混凝土孔隙腐蚀液中碳钢阻锈作用

Effect of calcium lignosulfonate on rust resistance of carbon steel in simulated concrete pore solution

周钰鑫 1季涛 1靳丁帅男 1施佳汇 1王海洲 1周鸣 1牛龙龙 1张士萍1
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作者信息

  • 1. 南京工程学院 建筑工程学院,江苏 南京 211167
  • 折叠

摘要

钢筋混凝土结构常因钢筋锈蚀而导致过早破坏,加入阻锈剂可以有效抑制钢筋锈蚀,提高钢筋混凝土结构耐久性.在模拟混凝土孔隙腐蚀液中加入不同浓度的木质素磺酸钙,通过开路电位、交流阻抗谱和动电位极化曲线研究其对碳钢的阻锈作用与机理.结果表明:在 3.5%NaCl、pH为12.5的腐蚀液中,木质素磺酸钙可提高开路电位、增大电荷转移电阻以及减小腐蚀电流密度,从而起到阻锈作用.同时,木质素磺酸钙在碳钢表面能够与氯离子竞争吸附,保护钝化膜,抑制腐蚀发展.

Abstract

Reinforced concrete structures are often damaged due to corrosion of steel bars.Adding inhibitors can effectively inhibit corrosion of steel bars and improve the durability of reinforced concrete structures.Here,the calcium lignosulfonate was added to the simulated concrete pore solution to study its inhibition effect and mechanism on carbon steel by open circuit potential,AC impedance spectroscopy and potentiodynamic polarization curves.The results showed that in the corrosive solution of 3.5%NaCl and pH12.5,the calcium lignosulfonate retarded the corrosion via increasing the open circuit potential,increaing the charge transfer resistance and reducing the corrosion current density.Besides,the calcium lignosulfonate molecular can compete with chloride ions for adsorption on the surface of carbon steel,and protect the passive film and inhibit the development of corrosion.

关键词

木质素磺酸钙/腐蚀模拟液/阻锈剂/氯离子/碳钢

Key words

calcium lignosulfonate/simulated corrosion solution/inhibitor/chloride ion/carbon steel

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基金项目

江苏省大学生实践创新训练计划重点项目(202111276021Z)

国家自然科学基金(52078247)

出版年

2024
混凝土
中国建筑东北设计研究院有限公司

混凝土

CSTPCD北大核心
影响因子:0.844
ISSN:1002-3550
参考文献量14
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