首页|碳酸化-水化耦合养护对不锈钢渣净浆力学性能和Cr离子溶出的影响

碳酸化-水化耦合养护对不锈钢渣净浆力学性能和Cr离子溶出的影响

Effect of carbonation-hydrated coupling mechanisms on mechanical properties and Cr leachability of stainless steel slag

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在CO2 浓度为 99%,压力为 0.2 MPa条件下,对钢渣复合胶凝材料进行碳酸化-水化耦合养护,调节碳酸化-水化耦合机制和碳酸化时间,分析硬化浆体的抗压强度、固碳量、矿物组成、微观形貌以及Cr离子溶出规律.结果表明钢渣/水泥试块标准养护 3 d后进行碳酸化养护,3 d和 28 d强度均达到最高.水化养护 3d后进行碳酸化养护 1 h、2 h、6 h,可使 3 d的抗压强度提升16.3%、26.5%、50.2%,后期水化强度持续增长,28 d强度分别提高 17.6%、27.7%、22.8%且安定性良好.水化养护 28 d后进行碳酸化的试块固碳量最高,这是因为水化养护 3 d后进行碳化,参与碳化反应的主要是C2S、C3S等,水化养护 28 d后进行碳化,参与碳酸化反应的主要是C-S-H凝胶、Ca(OH)2,及未反应的C2S、C3S等.C-S-H凝胶和Ca(OH)2 碳化活性较高,固碳能力强,但碳化产物强度较低.不同的碳酸化-水化耦合机制对Cr离子的固化作用也有显著的影响,水化养护 3 d后进行碳酸化处理的固化效果最好,碳酸化养护 6 h的试块,Cr离子溶出降低58.2%.
It aimed to investigate the effect of carbonation-hydration coupling curing mechanism on the CO2 uptake,compressive strength,volume stability and Cr leaching of cement paste containing high content of stainless steel slag.Cement paste was exposed to CO2(99.9%,0.2 MPa)for carbonation curing after hydration for 3 d,7 d and 28 d.The results indicated that carbonation-hydration procedure has a significant impact on the compressive strength of hardened paste.Hardened pasted carbonation curing for 1 h,2 h,and 6 h after hydration curing for 3 d can increase the compressive strength by 16.3%,26.5%,and 50.2%,and the hydration reaction will continue and impart the paste a continuously increasing compressive strength.The compressive strength of 28 d increased by 17.6%,27.7%,22.8%.The CO2 uptake and Cr leaching of the paste also depends on carbonation-hydration coupling curing mechanism.C2S,C3S and the hydration products(C-S-H gel and Ca(OH)2)can react with CO2 to form stable calcium carbonate.C-S-H gel and Ca(OH)2 show better carbonation activity than that of C2S,C3S,thereby samples exposed to CO2 after 28 d hydration curing absorb most CO2.Carbonation-hydration curing show excellent solidification effect on Cr from stainless steel slag,and the Cr leaching of samples carbonated for 6 h after hydration for 3 d decreased by 58.2%compared to the reference samples.

stainless steel slagcarbonationmechanical propertycarbonation productsCr

房延凤、姚淑红、王庆贺、尚小朋、丁向群、佟钰

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沈阳建筑大学材料科学与工程学院, 辽宁 沈阳 110168

沈阳建筑大学土木工程学院, 辽宁 沈阳 110168

山东城市建设职业学院 建筑工程系, 山东 济南 250103

不锈钢渣 碳酸化 力学性能 碳化产物 Cr

国家自然科学基金辽宁省教育厅科学研究经费项目

52378252lnjc202017

2024

混凝土
中国建筑东北设计研究院有限公司

混凝土

CSTPCD北大核心
影响因子:0.844
ISSN:1002-3550
年,卷(期):2024.(2)
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