混凝土2024,Issue(4) :58-62,102.DOI:10.3969/j.issn.1002-3550.2024.04.012

碳酸化钢渣磷石膏复合胶凝材料及其力学性能研究

Preparation of composite cementitious material with carbonation steel slag and phosphogypsum and its mechanical properties

刘凤东 饶美娟 丁庆军
混凝土2024,Issue(4) :58-62,102.DOI:10.3969/j.issn.1002-3550.2024.04.012

碳酸化钢渣磷石膏复合胶凝材料及其力学性能研究

Preparation of composite cementitious material with carbonation steel slag and phosphogypsum and its mechanical properties

刘凤东 1饶美娟 1丁庆军1
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作者信息

  • 1. 武汉理工大学材料科学与工程学院,湖北武汉 430070
  • 折叠

摘要

为了提高磷石膏胶凝材料的力学性能,采用钢渣的碳酸化活性固化磷石膏制备了复合胶凝材料.研究了钢渣的碳酸化活性与钢渣与磷石膏相对比例对复合胶凝材料力学性能的影响,探讨了碳酸化钢渣和磷石膏之间的相互作用机制.研究表明:钢渣具有极高的碳酸化活性,随着钢渣掺量的增加,复合胶凝材料力学性能显著提高;当钢渣掺量大于40%时,复合胶凝材料抗压强度大于70 MPa,软化系数大于0.87.机理分析表明:磷石膏粉隔离了钢渣粉,提高了钢渣粉颗粒间距,使单颗粒钢渣粉的碳酸化反应更为充分.同时钢渣碱性物质与磷石膏酸性物质中和会降低体系碱度,钢渣浸出的钙离子可结合磷石膏中氟离子和磷酸根离子,对有害离子起到化学固化作用.

Abstract

Steel slag and phosphogypsum are two typical types of solid waste which were used to prepare composite cementitious ma-terial.The influence of carbonation activity of steel slag and the relative ratio of steel slag to phosphogypsum on the mechanical proper-ties of composite cementitious material was studied,and the solidification mechanism of carbonated steel slag on phosphogypsum was explored.The results indicate that steel slag possesses extremely high carbonation activity,and with the increase of steel slag content,the mechanical properties of composite cementitious material gradually improve.When the steel slag content is more than 40%,the compres-sive strength of composite cementitious material is more than 70 MPa,the softening coefficient of composite cementitious material is higher than 0.87.For the isolation effect of phosphogypsum powder the carbonation reaction of single particle of steel slag powder in-creases.Moreover,the neutralization of alkaline substances in steel slag and acidic substances in phosphogypsum reduces the alkalinity of the system.The calcium ions leached from steel slag combine with fluorine ions and phosphate ions in phosphogypsum,playing a chemi-cal solidification role in harmful ions.

关键词

磷石膏/钢渣/碳酸化/活性/力学性能

Key words

phosphogypsum/steel slag/carbonation/activity/mechnical properties

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基金项目

固废资源化利用与节能建材国家重点实验室开放基金(SWR-2022-006)

出版年

2024
混凝土
中国建筑东北设计研究院有限公司

混凝土

CSTPCD北大核心
影响因子:0.844
ISSN:1002-3550
参考文献量6
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