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基于响应面法设计与制备磷石膏矿渣基复合胶凝材料

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为了促进磷石膏等固废材料的资源化利用,优化设计和制备了力学强度满足P·O 42.5级水泥规范要求的胶凝材料,基于响应面法对磷石膏-矿渣-石灰-锂渣-钢渣五元体系进行试验设计,分别以3 d、7 d和28 d抗压强度为响应值,探究磷石膏矿渣基复合胶凝材料力学性能的变化规律,建立了磷石膏矿渣基复合胶凝材料力学性能预测模型.结果表明最优配合比为磷石膏 33.86%,矿渣39.13%,石灰2.28%,锂渣20.1%,钢渣4.65%,胶凝材料的3 d、7 d和28 d抗压强度分别达到18.8 MPa、32.3 MPa、50.3 MPa,满足P·O 42.5 级水泥规范要求,并且实测值与预测值的相对误差绝对值均小于 5%,说明基于响应面法优化设计磷石膏矿渣基复合胶凝材料具有可行性.
Optimal design and preparationof phosphogypsum-slag-based composite cementitious materials based on response surface methodology
In order to promote the resource utilization of phosphogypsum and other solid wastes,it optimized the design and preparation of cementable materials meeting the requirements of P·O 42.5 cement specification.Taking 3 d,7 d and 28 d compressive strength as response values,the change law of mechanical properties of phosphogypsum slag based composite cementing materials was explored,and the prediction model of mechanical properties of phosphogypsum slag based composite cementing materials was established.The results showed that the optimal mix ratio was:phosphogypsum 33.86%,slag 39.13%,lime 2.28%,lithium slag 20.1%,steel slag 4.65%,the 3 d,7 d and 28 d compressive strength of cementing materials reached 18.8 MPa,32.3 MPa,50.3 MPa,respectively,meeting the requirements of P·O 42.5 cement specification.The absolute value of the relative error between the measured value and the predicted value is less than 5%,indicating that it is feasible to optimize the design of phosphogypsum slag based composite cementing material based on response surface method.

phosphogypsumcomposite cementitious materialresponse surface methodologymechanical strength

李悦、谢东、林辉

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北京工业大学 城市与工程安全减灾教育部重点实验室,北京 100124

磷石膏 复合胶凝材料 响应面法 力学强度

国家重点研究计划课题

2022YFC3803102

2024

混凝土
中国建筑东北设计研究院有限公司

混凝土

CSTPCD北大核心
影响因子:0.844
ISSN:1002-3550
年,卷(期):2024.(7)
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