混凝土2024,Issue(8) :102-105.DOI:10.3969/j.issn.1002-3550.2024.08.019

纳米C-S-H的合成及其对普通硅酸盐水泥早期水化的影响

Synthesis of nano C-S-H and its effect on early hydration of Portland cement

赵双 张丽敏 王新程 房延凤
混凝土2024,Issue(8) :102-105.DOI:10.3969/j.issn.1002-3550.2024.08.019

纳米C-S-H的合成及其对普通硅酸盐水泥早期水化的影响

Synthesis of nano C-S-H and its effect on early hydration of Portland cement

赵双 1张丽敏 2王新程 3房延凤2
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作者信息

  • 1. 东北大学辽宁沈阳 110819
  • 2. 沈阳建筑大学,辽宁沈阳 110168
  • 3. 中国建筑第六工程局有限公司,天津 300457
  • 折叠

摘要

为提高水泥基材料的早期强度,制备了纳米C-S-H悬浮液,并通过XRD和Zeta电位对其组成和粒度分布、稳定性进行了分析.通过水化放热、热重分析和扫描电子显微镜扫描电镜(SEM)研究了纳米C-S-H对硅酸盐水泥早期强度发展、水化放热、水化产物的影响.结果表明:合成了具有半结晶结构的稳定的纳米C-S-H悬浮液.纳米C-S-H的加入促进了C3S的水化,尤其是在前24 h,并使水泥的水化诱导期明显缩短.含有0.05%纳米C-S-H砂浆的8 h、16 h和24 h抗压强度分别提高了176.0%、145.6%和43.9%,与此同时,砂浆的3 d抗压强度没有明显减少.

Abstract

To improve the early strength of cement-based materials,nano C-S-H suspensions were prepared and characterized by XRD and Zeta potential.And the effects of nano C-S-H on the exothermic heat of early hydration,strength development and hydration products of Portland cement were studied by hydration exothermic,thermo gravimetry(TG)analysis and scanning electron microscope(SEM).The results showed that stable nano C-S-H with a semi-crystalline structure were prepared.The TG and SEM analysis indicated that the addition of nano C-S-H accelerate the hydration of C3S,especially in the first 24 h and the hydration induction period is significantly shortened.The 8 h,16 h and 24 h compressive strength of mortars containing nano C-S-H increased by 176.0%,145.6%and 43.9%,respectively,compared with the reference mortar.Meanwhile,there was no significant reduction in 3d compressive strength.

关键词

纳米C-S-H/水泥/水化/早强/微观形貌

Key words

nano C-S-H/cement/hydration/early strength/micro morphology

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基金项目

国家自然科学基金(51808354)

中国博士后科学基金(2018M641712)

辽宁省教育厅2020年科研计划项目(lnjc202017)

辽宁省科技厅博士启动基金(2021-BS-165)

出版年

2024
混凝土
中国建筑东北设计研究院有限公司

混凝土

CSTPCD北大核心
影响因子:0.844
ISSN:1002-3550
参考文献量7
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