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不同龄期下磷酸镁水泥的力学特性与微观演变机制研究

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利用单轴压缩试验从宏观尺度探究了不同养护龄期下磷酸镁水泥(MPC)的力学破坏特征,并从MPC的物相组成、微观结构和微观力学性能演变角度揭示了其微观机制,得到主要结论:MPC随龄期的增长逐渐由剪切-张拉复合型塑性破坏向张拉型脆性断裂转化;随着龄期的增长,MPC中物相MKP晶体含量有大幅增加,非晶相水化产物和未反应MgO含量逐渐下降,MPC内部整体孔隙率几乎不变,但孔隙结构却不断细化;MPC宏观强度随龄期的不断增大主要取决于孔隙结构的不断密实,而非水化产物微观力学性能的影响.
Mechanical properties and micro-evolution mechanism of magnesium phosphate cement at different curing ages
The mechanical damage characteristics of magnesium phosphate cement(MPC)were investigated from the macroscopic scale by using uniaxial compression test at different curing ages,and the microscopic mechanisms were revealed from the perspectives of the phase composition,microstructure and micromechanical properties evolution,and the following conclusions were obtained:MPC gradually transforms from shear-tension plastic damage to tensile brittle fracture as curing age increases.With the increasingcuring age,the content of MKP crystals in MPC increases,the content of amorphous phase hydration products and unreacted MgO gradually decreases,and the overall porosity within MPC is almost unchanged,but the pore structure is continuously refined.The continuous increase of the macroscopic strength of MPC with the increasing curing age is mainly dependent on the continuous densification of the pore structure rather than the effect of the microscopic mechanical properties of the hydration products.

magnesium phosphate cementdamage characteristicsmicrostructurehydration productsmicromechanical properties

栾海涛、宋奇达、王涛、陈佳俊、凌研方、马子翔、周子涵

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北京城建集团有限公司,北京 100088

清华大学土木工程系,北京 100084

磷酸镁水泥 破坏特征 微观结构 水化产物 微观力学性能

2024

混凝土
中国建筑东北设计研究院有限公司

混凝土

CSTPCD北大核心
影响因子:0.844
ISSN:1002-3550
年,卷(期):2024.(11)