首页|纳米水化硅酸钙对水泥早期水化及强度的影响

纳米水化硅酸钙对水泥早期水化及强度的影响

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纳米水化硅酸钙由于能极大地促进水泥早期的水化速度而被广大学者研究,但大多研究均针对纯水泥,对于其在复合胶凝材料体系中的应用研究却很少.通过微量热、XRD、MIP、电导率、胶砂强度等测试方法,研究了纳米水化硅酸钙对纯水泥、掺粉煤灰和矿粉3个体系早期水化进程和强度发展的影响.结果表明:纳米水化硅酸钙对水泥早期的水化进程有明显的加速效果,特别是12 h之前的水化龄期,这种加速效果持续到24 h后变得不明显.纳米水化硅酸钙能加速C3S和C3A矿物1 d前的反应速率,3 d后C3S的反应速率降低,其矿物含量高于对比样.纳米水化硅酸钙使得水泥12 h胶砂抗压强度提升100%以上,对后期水泥抗压强度没有明显影响.
Effect of nano C-S-H on early hydration and strength of cement with different mineral admixture
Nano-calcium silicate hydrate has been studied by many researchers because it can greatly promote the hydration rate of cement in the early age.But the most studies are focused on pure cement,and there are few researches on its application in composite cementitious material system.The effects of nano-calcium silicate hydrate on the early hydration process and strength development of cement containing fly ash and granulated blast furnace slag were studied by isothermal calorimetry test,X-Ray diffraction test(XRD),electrical conductivity,mercury intrusion porosimetry(MIP)and compressive strength test.The results show that the nano-calcium silicate hydrate has obvious accelerating effect on the early hydration process of cement,especially before 12 hours.Then the accelerating effect becomes insignificant after 24 hours.The positive effect of nano-calcium silicate on cement is mainly due to the promoting effect on reaction of C3S and C3A minerals before 1 day,then the reaction rate of C3S decreased after 3 days and its content is higher than that of the comparison sample.At the early stage of hydration,the compressive strength increases more than doubled because of promoting effect of nano-calcium silicate hydrate and there is no obvious effect on compressive strength of cement in later age.

nano-calcium silicate hydratehydration processhydration productsearly compressive strengthmineral admixture

陈稳、张心源、倪陈新、苏昂、姜骞、于诚

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江苏省交通工程建设局,江苏南京 210000

江苏苏博特新材料股份有限公司高性能土木工程材料国家重点实验室,江苏南京 211103

纳米水化硅酸钙 水化进程 水化产物 早期强度 矿物掺合料

2024

混凝土
中国建筑东北设计研究院有限公司

混凝土

CSTPCD北大核心
影响因子:0.844
ISSN:1002-3550
年,卷(期):2024.(12)