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磷石膏基复合充填胶凝材料强度性能的分析研究

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为了提高磷石膏的综合资源利用率,结合镍矿充填需要,以磷石膏为基本材料,生石灰和矿渣微粉等固体废弃物为辅助材料开展替代水泥的新型复合充填胶凝材料的试验研究.通过正交试验研究分析磷石膏添加量对充填胶凝材料强度的作用.利用遗传规划获得磷石膏基复合充填胶凝材料强度规律的函数关系,使用遗传算法对回归函数进行有约束优化.结果显示:当生石灰为4.48%,磷石膏为32.42%,芒硝为2.35%,氢氧化钠为2.5%和渣粉为58.3%时,磷石膏基复合充填胶凝材料强度能够满足矿山充填需要.采用SEM和XRD分析了磷石膏复合充填胶凝材料的水化机理,水化产物主要是C-S-H凝胶和钙矾石,相比水泥对比试验,磷石膏基新型充填胶凝材料水化产生的钙矾石数量更多.氢氧化钠的加入能够加速水化反应的速度,增强充填体龄期抗压强度.随着养护时间的增加,水化产物不断增长,孔隙不断被填满,结构变的更加致密,使得充填体具有了较好的力学性能.
Research the strength properties of phosphogypsum based composite filling materials
In order to improve the comprehensive resource utilization of phosphogypsum,the experimental research of new composite filling cementitous materials that will be replaced the cement has been carried out,which uses the phosphogypsum as the basic material,the lime,slag powder and other solid waste as auxiliary materials based on the requirement of mine.The researchers use the orthogonal experimental to study the role of phosphogypsum addition for the strength of new composite filling cementitous materials.Obtained the strength rule function of new composite filling cementitous materials based on the phosphogypsum by genetic programming,then use the genetic alogrithms to optimize the regression function.The results shown the strength of new composite filling cementitous materials based on the phosphogypsum can meet the requirement of Mine when lime is 4.48%,phosphogypsum is 32.42%,glauber is 2.35%,sodium hydroxide is 2.5%and slag powder is 58.3%.Using the SEM and XRD to analysis the hydration mechanism of the new composite filling cementitous materials,the C-S-H gel and errringite are mainly hydration products.Comparing with the contrast test of cement,the hydration products of new composite filling cementitous materials based on the phosphogypsum have more errringite than cement.Sodium hydroxide is added to accelerate the speed of hydration,and enhance the filling body age compressive strength.With the increase of curing time,the hydration products are growing and constantly filled in the pore,so the structure becomes more dense and has more better mechanical properties.

phosphogypsumcomposite filling materialslaw of compressive strengthoptimization algorithm

吕淑莲、李茂辉

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宁夏建设职业技术学院建筑与艺术设计学院,宁夏银川 750021

北方民族大学材料科学与工程学院,宁夏银川 750021

磷石膏 复合充填材料 抗压强度规律 优化算法

2024

混凝土
中国建筑东北设计研究院有限公司

混凝土

CSTPCD北大核心
影响因子:0.844
ISSN:1002-3550
年,卷(期):2024.(12)