湖南有色金属2024,Vol.40Issue(6) :109-113.

波长色散X射线荧光光谱法测定锆石中12种元素的含量方法研究

Determination of 12 Elements in Zircon by Wavelength Dispersive X-ray Fluorescence Spectrometry

姚泽 黄绍念 胡榴 周瑾瑾 叶鹏 辛虹瑾
湖南有色金属2024,Vol.40Issue(6) :109-113.

波长色散X射线荧光光谱法测定锆石中12种元素的含量方法研究

Determination of 12 Elements in Zircon by Wavelength Dispersive X-ray Fluorescence Spectrometry

姚泽 1黄绍念 1胡榴 1周瑾瑾 1叶鹏 1辛虹瑾1
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作者信息

  • 1. 湖南省地质实验测试中心,湖南长沙 410007
  • 折叠

摘要

利用熔融法-XRF法测定锆石中无机元素的含量,采用了低稀释比方法进行熔融制样.使用的熔剂与样品的质量比为4∶1,制样时选择偏硼酸锂和四硼酸锂混合熔剂作为熔剂,在此条件下进行熔融矿样.准确称取样品,后使用铂-金坩埚进行熔样、注模、自然冷却.对于所测定锆石中的12项组分中,各组分相对标准偏差RSD<3%,相对误差<8%.同时本方法测量锆石中Zr元素与化学法对比相对偏差<1%,证明该方法能较好满足锆石中各元素的定量检测.

Abstract

The content of inorganic elements in zircon was determined by melting XRF method,and a low dilution ratio method was used for melting sample preparation.The mass ratio of the flux used to the sample is 4:1.When preparing the sample,a mixed flux of lithium metaborate and lithium tetraborate is selected as the flux,and the ore sample was melted under these conditions.Accurately weigh the sample,then use a platinum gold crucible for sample melting,injection molding,and natural cooling.For the 12 components in the determined zircon,the relative standard deviation(RSD)of each component is less than 3%,and the relative error is less than 8%.At the same time,the relative deviation between the measurement of Zr element in zircon by method and the chemical method is less than 1%,indicating that this method can effectively meet the quantitative detection of various elements in zircon.

关键词

锆石/无机元素/低倍稀释/熔融制样

Key words

zircon/inorganic elements/low dilution/melting sample preparation

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出版年

2024
湖南有色金属
湖南有色金属研究院,湖南有色金属学会

湖南有色金属

影响因子:0.393
ISSN:1003-5540
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