首页|预处理剂对水再生系统离子交换去除能力影响的研究

预处理剂对水再生系统离子交换去除能力影响的研究

扫码查看
笔者利用载人航天水再生系统地面设备开展尿液再生长期试验验证时,发现当预处理剂变化时,水再生系统的离子交换去除能力也会受影响.为此,我们通过小样试验、水质成分分析等手段研究了预处理剂变化对水再生系统离子交换去除能力的影响行为及机理.结果表明,伴随预处理剂中CrO3含量的增加,蒸馏水中有机酸含量增加,导致蒸馏水电导率升高、有机碳增加、pH值降低;有机酸在水中离解度低,且其酸根离子与强碱阴离子交换树脂发生交换反应时选择性系数低,导致离子交换速率慢,随着蒸馏水中有机酸含量增加,酸根离子交换带会变宽、后移而发生穿透,使水再生系统的离子交换去除能力降低.
Study on the effect of pretreatment agents on the ion exchange removal capacity of water regeneration systems
When conducting long-term experimental verification of urine regeneration using ground equipment of manned space water regeneration system,it was found that the ion exchange removal ability of the water regeneration system is also affected when the pre-treatment agent changes.Therefore,the influence behavior and mechanism of pre-treatment agent changes on the ion exchange removal capacity of water regeneration systems were studied through small sample experiments,water quality composition analysis,and other means.The results showed that with the increase of CrO3 content in the pre-treatment agent,the organic acid content in distilled water increased,leading to an increase in the conductivity,an increase in the organic carbon content,and a decrease in pH value of distilled water.Organic acids have low degree of dissociation in water,and their selectivity coefficients are low when exchanging with strong alkaline anion exchange resins.This results in a slow ion exchange rate of the acid ion.As the organic acid content in distilled water increases,the ion exchange band of acid ion widens and shifts backwards,causing resin penetration,resulting in a decrease in the ion exchange removal ability of the water regeneration system.

water regenerationpre-treatment agentdistilled waterion exchange resinimpact mechanism

曹适意、李英斌、丁平、王俊峰、杨松林、熊涛

展开 >

人因工程全国重点实验室,北京 100094

中国航天员科研训练中心,北京 100094

水再生 预处理剂 蒸馏水 离子交换树脂 影响机理

2024

航天医学与医学工程
中国航天员科研训练中心

航天医学与医学工程

影响因子:0.392
ISSN:1002-0837
年,卷(期):2024.35(6)