淮阴师范学院学报(自然科学版)2024,Vol.23Issue(3) :239-246.

制备WO3/TS-1分子筛及催化环戊烯环氧化反应研究

Preparation of WO3/TS-1 Molecular Sieve and the Study on the Epoxidation Properties of Catalytic Cyclopentane

王雅 马豪杰 王思雨 吴航 赵家和 张浩洋
淮阴师范学院学报(自然科学版)2024,Vol.23Issue(3) :239-246.

制备WO3/TS-1分子筛及催化环戊烯环氧化反应研究

Preparation of WO3/TS-1 Molecular Sieve and the Study on the Epoxidation Properties of Catalytic Cyclopentane

王雅 1马豪杰 1王思雨 1吴航 1赵家和 1张浩洋1
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作者信息

  • 1. 淮阴师范学院化学化工学院,江苏淮安 223000
  • 折叠

摘要

利用湿法浸渍制备了一系列WO3/TS-1分子筛.利用SEM、TEM、XRD、IR、UV-Vis、XPS、BET、ICP等多种分析手段对催化剂的结构、形貌和性质等进行了表征.考察了这一系列分子筛对环戊烯环氧化反应的催化性能,其中以W占分子筛质量分数为4%时浸渍制备的分子筛的催化性能最好.催化剂循环4次后,1,2-环氧环戊烷的选择性和产率保持在68.7%和55.5%左右.

Abstract

A series of WO3/TS-1 zeolites were prepared by wet impregnation using hierarchical TS-1 as a carrier.SEM,TEM,XRD,IR,UV-Vis,XPS,BET,ICP and other analytical methods were used to characterize the structure,morphology and properties of the catalyst.The catalytic performance of this series of zeolite in the epoxidation of cyclopentane was investigated.The best catalytic performance was obtained when the mass fraction of W was 4%.After the catalyst was cycled four times,the selec-tivity and yield of 1,2-epoxycyclopentane were keeped at 68.7%and 55.5%.

关键词

WO3/TS-1分子筛/合成/环戊烯/环氧化

Key words

WO3/TS-1 zeolites/synthesis/cyclopentane epoxidation

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基金项目

江苏省高校基础科学(自然科学)研究面上项目(23KJB150005)

大学生创新创业训练计划项目(202210323066Y)

出版年

2024
淮阴师范学院学报(自然科学版)
淮阴师范学院

淮阴师范学院学报(自然科学版)

影响因子:0.259
ISSN:1671-6876
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