首页|络合沉淀法—硫化沉淀法联合处理铜氰贫液试验研究

络合沉淀法—硫化沉淀法联合处理铜氰贫液试验研究

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针对某黄金生产企业产生的铜氰贫液,采用络合沉淀法—硫化沉淀法联合进行回收处理.在络合沉淀法五水合硫酸铜投加量3.0 g/L、焦亚硫酸钠投加量2.0 g/L,硫化沉淀法九水合硫化钠加药量0.35 g/L条件下,铜氰贫液中总氰化合物、铜和硫氰酸盐质量浓度从150.84 mg/L、121.46 mg/L、252.65 mg/L 降至 0.44 mg/L、86.17 mg/L、1.23 mg/L,回收金、银、铜的产值为116.62元/m3,扣除药剂成本后产生经济效益55.44元/m3.研究结果为类似氰化企业铜氰贫液的净化处理提供参考.
Experimental study on complex precipitation-sulfide precipitation joint treatment of copper cyanide barren solution
In response to the copper cyanide barren solution generated by a gold production company,a joint recovery treatment using complex precipitation and sulfide precipitation was adopted.Under the conditions of adding 3.0 g/L of copper sulfate pentahydrate and 2.0 g/L of sodium metabisulfite in the complex precipitation process,and adding 0.35 g/L of sodium sulfide nonahydrate in the sulfide precipitation process,the mass concentrations of total cyanide compounds,copper,and thiocyanate in the copper cyanide barren solution decreased from 150.84 mg/L,121.46 mg/L,252.65 mg/L to 0.44 mg/L,86.17 mg/L,1.23 mg/L,respectively.The production value of gold,silver,and copper recovery was 116.62 yuan/m3,generating an economic benefit of 55.44 yuan/m3 after deducting the cost of reagents.The research results provide a reference for the purification treatment of similar cyanide barren solutions in cyanide enterprises.

copper cyanide barren solutioncomplex precipitationsulfide precipitationjoint treatmenttotal cya-nide compounds

刘强、伍赠玲、高世康、王弘、韩良、林国钦

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浙江大学环境与资源学院

紫金矿业集团股份有限公司

铜氰贫液 络合沉淀 硫化沉淀 联合处理 总氰化合物

国家自然科学基金项目

41721001

2024

黄金
长春黄金研究院

黄金

CSTPCD
影响因子:0.446
ISSN:1001-1277
年,卷(期):2024.45(2)
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