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摇床法制备单分散多孔聚苯乙烯微球的研究

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采用摇床法,以聚乙烯吡咯烷酮为分散剂,水及无水乙醇为反应介质,偶氮二异丁腈为引发剂,通过分散聚合制备出单分散聚苯乙烯微球,并通过两步溶胀法制备出多孔聚合物微球.对影响微球粒径、单分散性及其形貌的因素进行研究,结果显示,采用简单的摇床法可以实现单分散聚苯乙烯微球的批量、可控制备;微球粒径可控制在2~3 μm,并具有良好的单分散性和球形形貌结构;通过两步溶胀法制备的微球可观察到明显的孔隙结构.
Preparation of Monodisperse Porous Polystyrene Microspheres By Shaker Method
In this paper,the shaker method,with polyvinylpyrrolidone as dispersant,water and absolute ethanol as reaction medium,azo diisobutyronitrile initiator,by dispersing polymerization to prepare mono-disperse polystyrene microspheres,and through a two-step swelling method were used to prepare porous polymer microspheres.The factors affecting the particle size,monodispersity and morphology of micro-spheres were studied.The results show that the batch preparation of monodisperse polystyrene micro-spheres can be achieved by simple shaker method.The particle size of the microspheres can be controlled at 2~3 µm,and the microspheres have good monodispersity and spherical morphology.Obvious pore struc-ture was observed in the microspheres prepared by two-step swelling method.

shaker methoddispersion polymerizationpolystyrene microspheresmicrosphere morphology

王楠、张高文

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湖北工业大学绿色轻工材料湖北省重点实验室,湖北武汉 430068

摇床法 分散聚合 聚苯乙烯微球 微球形貌

2024

湖北工业大学学报
湖北工业大学

湖北工业大学学报

CHSSCD
影响因子:0.258
ISSN:1003-4684
年,卷(期):2024.39(4)
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