摘要
为探究SLS(木质素磺酸钠)对市政污泥好氧发酵重金属(Cr、Zn、Pb、Cu)钝化的影响,分别添加物料总质量0%、5%、10%、15%的SLS(标记为CK、SLS5、SLS10、SLS15)与市政污泥进行好氧发酵,并通过Pearson系数和冗余分析对理化因素与重金属开展相关性分析.重金属分析显示,添加SLS的处理组对重金属钝化效果均优于CK组,其中SLS5组对Cr、Zn、Pb钝化效果最好,钝化率分别为81.46%、32.58%、98.61%,SLS15组对Cu钝化效果最好,钝化率为41.67%.Pearson系数和冗余分析表明,Cr、Zn、Pb、Cu重金属生物有效性均与OM(有机质)呈极显著的正相关(P<0.01),而SLS5组OM的质量分数在各实验组中是最低的.在此研究条件下,添加5%的SLS对市政污泥好氧发酵重金属钝化效果最佳.
Abstract
To investigate the effect of SLS(sodium lignosulfonate)on heavy metals(Cr,Zn,Pb,Cu)in municipal sludge aerobic fermentation,the municipal sludge and SLS with total material mass of0%,5%,10%,15%(labeled CK,SLS5,SLS10,SLS15)were added for aerobic fermentation,and correlation analysis between physicochemical factors and heavy metals was carried out through Pearson and redundancy analysis.Heavy metal analysis shows that the SLS group has a better passivation effect on heavy metals than the CK group.The SLS5 group has the best passivation effect on Cr,Zn and Pb with passivation rates of 81.46%,32.58%and 98.61%,respectively.The SLS15 group has the best passivation effect on Cu with a passivation rate of 41.67%.Pearson and redundancy analysis show that the bioavailability of heavy metals such as Cr,Zn,Pb and Cu is positively correlated with OM(organic matter)(P<0.01),and the mass fraction of OM in SLS5 group is the lowest among all groups.Under this condition,adding 5%SLS has the best effect on the passivation of heavy metals in municipal sludge aerobic fermentation.
基金项目
广西科技基地和人才专项(桂科AD22035001)
南宁市优秀青年科技创新创业人才培育项目(RC20200108)
南宁市科学研究与技术开发计划(20183045-2)