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一种基于蛭石的多维度改性研究

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基于蛭石特有的层状结构及高温膨胀特性,研究不同浓度、不同种类的无机盐添加剂对不同粒径蛭石的改性影响,从多维度提高改性蛭石高温下的膨胀倍数,并进行微观形貌和物相组成分析.研究结果表明:在相同温度条件下,添加NaHCO3和KCl无机盐的改性蛭石体积膨胀率高于未改性蛭石.当添加相同浓度的NaHCO3和KCl时,随着蛭石粒径从0.2 mm增加到0.8 mm,在100-900℃温度范围内,改性蛭石的体积膨胀倍数随温度升高而增加,随粒径增加而增加,且添加KCl的改性效果优于添加NaHCO3.随着这2种无机盐添加剂浓度的逐渐增加,改性蛭石的膨胀倍数均呈现先增加后降低的趋势.
Research on multidimensional modification based on vermiculite
Based on the unique layered structure and high-temperature expansion characteristics of vermiculite,the effects of different concentrations and types of inorganic additives on the modification of vermiculite with different particle sizes were investigated to improve the expansion multiplier of modified vermiculite at high temperature from multiple dimensions.The microscopic morphology and phase composition of various types of modified vermiculite were analyzed.The results show that the volume expansion of modified vermiculite with NaHCO3 and KCl is higher than that of unmodified vermiculite under the same temperature conditions.When the same concentrations of NaHCO3 and KCl are added,with the increase of vermiculite particle size from 0.2 mm to 0.8 mm,the volume expansion multiples of modified vermiculite increase with the increase of temperature and with the increase of particle size in the temperature range of 100-900 ℃,and the modification effect of adding KCl is better than that of adding NaHCO3.With the gradual increase of the concentrations of these two inorganic salt additives,the expansion multiples of modified vermiculite both show a trend of first increasing and then decreasing.

vermiculiteinorganic saltsmultidimensional modificationheat treatmentexpansion multiple

张子夏、文贤馗、钟晶亮、李翔、廖强强

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上海电力大学上海市电力材料防护与新材料重点实验室,上海 200090

贵州电网有限责任公司电力科学研究院,贵州贵阳 550002

蛭石 无机盐 多维度改性 热处理 膨胀倍数

贵州省科技支撑计划贵州省科技支撑计划

黔科合支撑[2022]一般012一般015

2024

化学工程
华陆工程科技有限责任公司

化学工程

CSTPCD北大核心
影响因子:0.438
ISSN:1005-9954
年,卷(期):2024.52(3)
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