首页|盐酸溶液浸提-离子色谱法测定中溶盐石膏的含量

盐酸溶液浸提-离子色谱法测定中溶盐石膏的含量

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为更好地服务水利水电工程、岩土工程等行业土料勘察工作,建立了盐酸溶液浸提-离子色谱法测定中溶盐石膏(CaSO4·2H2O)含量的新方法.实验采用4.5mM Na2CO3/1.4mM NaHCO3淋洗液,在1.0mL·min1流速下对硫酸盐进行测定,测定方法的相对标准偏差(RSD)为2.3%,加标回收率为91.0%~102%,检出限为0.003g·kg-1.该方法操作简单、高效、准确度高,适用于工程勘察中大批量样品的测定.
Determination of dissolved salt gypsum by ion chromatography with hydrochloric acid solution extraction
In order to better serve the soil investigation work in water conservancy and hydropower engineering,geotechnical engineering and other industries,a new method for the determination of dissolved salt gypsum(CaSO4· 2H2O)was established by ion chromatography with hydrochloric acid solution extraction.Sulfate was determined with 4.5mM Na2CO3/1.4mM NaHCO3 eluent at a flow rate of 1.0mL·min-1.The relative standard deviation(RSD)of the method was 2.3%,the recovery was 91.0%~102%,and the detection limit was 0.003g·kg-1.This method was simple,high sensitivity and accuracy,and was suitable for the determination of large quantities of samples in engineering investigation.

hydrochloric acid solutionion chromatographydissolved salt gypsumengineering

贾亮亮、董凌云、郝兴华

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河北省水文工程地质勘查院,河北石家庄 050021

保定学院,河北保定 071000

盐酸溶液 离子色谱法 中溶盐石膏 工程

河北省地方标准制修订项目(2021)

GY202102

2024

化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
年,卷(期):2024.38(2)
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