首页|贵金属负载型TiO2光催化法处理含酚工业废水研究

贵金属负载型TiO2光催化法处理含酚工业废水研究

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以钛酸丁酯作为前驱体,采用溶胶凝胶法制备了纯TiO2,通过溶液静置法制备了不同质量分数的Ag/TiO2,通过XRD和TEM表征了催化剂物相结构和形貌特征.以苯酚为模拟污染物,研究了 Ag负载量、光照强度、苯酚起始浓度以及催化剂重复使用性能.实验结果表明,Ag负载量为2%、光照强度为400W、废水样品中苯酚浓度小于400mg·L-1时的催化降解效果最好,且催化剂在8次循环使用后催化活性仍保持较高水平.TEM和XRD表征分析发现,成功合成了 TiO2催化剂,Ag纳米粒子均匀分散在TiO2表面.
Treatment of phenol containing industrial wastewater by noble metal supported TiO2 photocatalysis
In this paper,pure TiO2 was prepared by sol-gel method with butyl titanate as precursor,and Ag/TiO2 with different mass fractions were prepared by solution standing method.The phase structure and morphology of the catalyst were characterized by XRD and TEM.Using phenol as a simulated pollutant,the loading amount of Ag,light intensity,initial concentration of phenol,and catalyst reusability were studied.The experimental results showed that the catalytic degradation effect was best when the Ag loading amount was 2%,the light intensity was 400W,and the phenol concentration in the wastewater sample was less than 400mg·L-1.Moreover,the catalytic activity of the catalyst remained at a high level after 8 cycles of reuse.TEM and XRD characterization analysis found that TiO2 catalyst was successfully synthesized,and Ag nanoparticles were evenly dispersed on the surface of TiO2.

TiO2 photocatalysisphenolAg nanoparticlesphenolic industrial wastewater

黎文辉、黄建光、陈彩霞

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广东环科院环境科技有限公司,广东广州 510000

中山大学环境科学与工程学院,广东广州 510000

广州海关技术中心,广东广州 510000

TiO2光催化 苯酚 Ag纳米粒子 含酚工业废水

广东省科技计划

2019A050506016

2024

化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
年,卷(期):2024.38(2)
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