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多点亲和聚合修饰高磁饱和强度磁流体的性能研究

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以有机铁为原料、有机碱为反应剂、N-甲基吡咯烷酮为反应溶剂制备纳米Fe3O4 磁性颗粒,并对磁粉进行共聚物表面改性,以使磁粉在高磁粉含量条件下仍可均匀稳定地与癸烯均聚体基载液形成磁流体体系.采用振动样品磁强计、透射电镜、激光粒度仪、Zeta电位仪、红外光谱仪等对磁粉进行表征与分析,并对癸烯均聚体基磁性流体的稳定性进行分析.结果发现,经表面共聚物修饰的磁粉所制备的磁性流体在外加 1.2T磁场作用下1400h后仍未产生磁液分离现象,磁饱和强度达到 700GS以上.
Study on preparation of high magnetic saturation strength magnetic fluid by multi-point affinity polymerization modification
Magnetic nanoparticles of Fe3O4 were prepared by using organic iron as raw material,organic alkali as reactant,and N-methylpyrrolidin-2-one as reaction solvent,and the magnetic powder was modified with a copolymer.Thus,under high magnetic particle content conditions,the magnetic powder could still form a magnetic fluid system uniformly and stably with the decane homopolymer based carrier liquid.The magnetic powder was characterized and analyzed by vibrating sample magnetometer,transmission electron microscope,laser particle size analyzer,zeta potentiometer,infrared spectrometer,etc.and the stability of decane homopolymer based magnetic fluid.It was found that the magnetic fluid was analyzed prepared by the surface copolymer modified magnetic powder did not undergo magnetic-liquid separation after 1400 hours,and the magnetic saturation strength was over 700GS.

magnetic fluiddecane homopolymermultipoint affinity polymerization modificationhith magnetic saturation

黄波、布和巴特尔、张晓臣、李鹏、迟佳龙

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黑龙江省科学院 高技术研究院,黑龙江 哈尔滨 150078

黑龙江工程学院 材料与化学工程学院,黑龙江 哈尔滨 150050

磁性流体 癸烯均聚体 多点亲和聚合修饰 高磁饱和强度

黑龙江省省属科研院所科研业务费项目

ZNBZ2022GJS02

2024

化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
年,卷(期):2024.38(3)
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