首页|多孔秸秆碳磺酸催化纤维素水解研究

多孔秸秆碳磺酸催化纤维素水解研究

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以玉米秸秆为原料、NaOH为造孔剂,采用碳化-活化制备多孔秸秆碳磺酸(PSCSA),用于纤维素的水解.通过X射线衍射(XRD)、傅里叶红外光谱(FTIR)、N2吸脱附分析(BET)、扫描电子显微镜(SEM)等对PSCSA进行表征分析,表明PSCSA为不定形碳结构并有部分微弱的石墨结晶,含有羟基(-OH)、羧基(-COOH)、磺酸基(-SO3H),且表面为多孔形貌.在多孔秸秆碳磺酸添加量为2.5g·g-1(纤维素)、底物纤维素浓度为3mg·mL-1、190℃水解1h的条件下,多孔秸秆碳磺酸催化纤维素水解还原糖得率可达60.61%.
Study on cellulose hydrolysis catalyzed by porous straw carbon sulfonic acid
Porous straw carbon sulfonic acid was prepared by carbonization-activation for cellulose hydrolysis using corn stover as the raw material and NaOH as the pore-forming agent.The characterization of PSCSA by XRD,FTIR,BET and SEM showed that PSCSA was an amorphous carbon structure with some weak graphite crystals,and contains hydroxyl(-OH),carboxyl(-COOH),sulfonic acid group(-SO3H),and the surface is porous morphology.When the addition amount of porous straw carbon sulfonic acid was 2.5g·g-1(cellulose)and the concentration of substrate cellulose was 3mg·mL-1,the yield of reducing sugar obtained from cellulose hydrolysis catalyzed by porous straw carbon sulfonic acid was up to 60.61%at 190℃ for 1 hour.

cellulosehydrolysisporous straw carbon sulfonic acidreducing sugar

陆佳、苏小红、刘泽

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黑龙江省能源环境研究院,黑龙江哈尔滨 150027

纤维素 水解 多孔秸秆碳磺酸 还原糖

黑龙江省自然科学基金联合引导项目

LH2021B027

2024

化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
年,卷(期):2024.38(4)
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