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重质油催化裂化用催化剂的研制及性能评价

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催化裂化是提高重质油资源利用效率的一种常用加工技术,为了提高重质油资源催化裂化的效率,以Ni(NO3)2、FeCl3和脂肪酸为主要原料,制备出一种适用于重质油催化裂化的新型油溶性催化剂FN-1,并采用小型固定流化床装置考察了不同因素对重质油催化裂化反应的影响.实验结果表明,随反应温度的升高,重质油转化率逐渐增大,生成的汽油成分中烯烃和芳烃含量逐渐增大;随剂油质量比的逐渐增大,重质油转化率逐渐增大,汽油中异构烷烃和烯烃的含量逐渐减小,芳烃含量逐渐增大;随质量空速的逐渐增大,重质油转化率逐渐减小,汽油中异构烷烃和烯烃的含量逐渐增大,芳烃含量逐渐减小,但变化的幅度比较小.当重质油催化裂化的反应温度为520℃、剂油质量比为6、质量空速为15h-1时,重质油的转化率可以达到95.38%,催化裂化效果较好.
Development and performance evaluation of catalysts for heavy oil catalytic cracking
Catalytic cracking is a commonly used processing technology to improve the utilization efficiency of heavy oil resources.In order to improve the efficiency of catalytic cracking of heavy oil resources,a new oil soluble catalyst FN-1 suitable for heavy oil catalytic cracking was prepared using nickel nitrate,ferric chloride,and fatty acids as the main raw materials.The influence of different factors on the catalytic cracking reaction of heavy oil was investigated using a small fixed fluidized bed device.The experimental results showed that as the reaction temperature increased,the conversion rate of heavy oil gradually increased,and the content of olefins and aromatics in the generated gasoline components gradually increased;As the mass ratio of solvent to oil gradually increased,the conversion rate of heavy oil gradually increased,the content of isomeric alkanes and olefins in gasoline gradually decreased,and the content of aromatics gradually increased;As the mass space velocity gradually increased,the conversion rate of heavy oil gradually decreased,the content of isomers and olefins in gasoline gradually increased,and the content of aromatics gradually decreased,but the magnitude of the change was relatively small.When the reaction temperature for catalytic cracking of heavy oil is 520℃,the optimal mass ratio of catalyst to oil is 6,and the optimal mass space velocity is 15h-1,the conversion rate of heavy oil can reach 95.38%,indicating a good catalytic cracking effect.

heavy oilcatalytic crackingoil soluble catalystinfluencing factorsperformance evaluation

孙鹏

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中石油云南石化有限公司,云南安宁 650399

重质油 催化裂化 油溶性催化剂 影响因素 性能评价

中国石油科技创新基金

2021D-5218-0816

2024

化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
年,卷(期):2024.38(4)
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