首页|锂离子电池钴酸锂正极材料的改性研究进展

锂离子电池钴酸锂正极材料的改性研究进展

扫码查看
钴酸锂在锂离子电池正极材料的应用中受到广泛关注,但目前钴酸锂在脱嵌过程中仍存在不可逆的结构转变以及与电解质发生不良副反应等问题,从而导致电池容量的快速衰减.因此,通过改性技术提高钴酸锂正极材料的能量密度和循环稳定性是当前的重要任务.本文综述了钴酸锂目前存在的问题以及近年来对其进行改性的一些方法,如粒径优化、体相掺杂和表面修饰,有效的提高了钴酸锂材料在高工作电压下的结构稳定性和电池性能,并对钴酸锂材料的研究现状进行了总结和展望.
Research progress on modification of lithium cobalt oxide cathode material for lithium ion batteries
Lithium cobalt oxide has received extensive attention in the application of lithium ion battery cathode materials.However,there are still some problems such as irreversible structural phase transition and adverse side reactions with electrolytes during the deintercalation process of lithium cobalt oxide,which leads to the rapid decay of battery capacity.Therefore,it is an important task to improve the energy density and cycle stability of lithium cobalt oxide cathode materials by modification technology.In this paper,the existing problems of lithium cobalt oxide and some methods of modification in recent years are reviewed,such as particle size optimization,bulk phase doping and surface modification,which can effectively improve the structural stability and battery performance of lithium cobalt oxide materials under high operating voltage.The research status of lithium cobalt oxide materials is summarized and prospected.

lithium cobalt oxidebulk phase dopingsurface modification

张超博、高筠、田然

展开 >

华北理工大学化学工程学院,河北唐山 063210

钴酸锂 体相掺杂 表面修饰

河北省自然科学基金

E2020209183

2024

化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
年,卷(期):2024.38(4)
  • 34