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原子吸收光谱法测定土壤中铜、锌、镉含量

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文章研究了原子吸收光谱法测定土壤中铜、锌、镉含量的方法,优化了仪器测定条件、微波消解试剂等.铜的浓度在 0.05~0.4μg·mL-1 范围内线性相关系数r=0.99930,锌的浓度在 0.02~0.8μg·mL-1 范围内线性相关系数r=0.99940,镉的浓度在 0.2~2.4μg·L-1 范围内线性相关系数r=0.99840.加标回收率在 95.3%~104.6%之间,方法的相对标准偏差(n=6)在 0.87%~5.91%之间.通过对某农田 8 个土壤样品铜、锌、镉含量检测,建立了良好的方法,实验结果表明,该方法准确度高,精密度好,为监管部门提供了一定的参考.
Determination of copper,zinc and cadmium content in soil by AAS
This paper studied the determination of copper,zinc and cadmium in soil,and optimized the instrument measurement conditions,microwave digestion reagent,etc.The concentration of copper is linear from 0.05 to 0.4μg·mL-1,linear correlation coefficient r=0.99930;zinc concentration is from 0.02 to 0.8μg·mL-1,linear correlation coefficient r=0.99940;cadmium concentration is linear from 0.2 to 2.4μg·L-1,linear correlation r=0.99840.The recovery rate of the spike is between 95.3%and 104.6%,and the relative standard deviation of the method(n=6)is between 0.87%and 5.91%.Through the detection of copper,zinc and cadmium content in 8 soil samples of a farmland,a good method is established.The experimental results show that the method has high accuracy and good precision,which provides a certain reference for the regulatory authorities.

atomic absorption spectroscopysoilheavy metalmicrowave digestion

赵美

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榆林职业技术学院 化学工程系,陕西 榆林 719000

原子吸收光谱法 土壤 重金属 微波消解

榆林职业技术学院校级科研项目

K202125

2024

化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
年,卷(期):2024.38(5)