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顶空-气相色谱质谱法测定地表水中5种有机胺类物质

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建立了顶空-气相色谱质谱法同时测定地表水中 5 种有机胺类物质的分析方法,并对顶空体系参数进行了优化.5 种有机胺类物质在 0.10~50.0mg·L-1 浓度范围内线性良好,3种浓度水样的平均加标回收率为 88.0%~104.5%,6 次测试结果相对标准偏差均小于 5%.本方法操作简便,检出限低,准确度和精密度良好,可满足地表水、地下水等水体中有机胺类物质的检测要求.
Determination of five organic amine substances in surface water by Headspace-GC-MS
A headspace gas chromatography-mass spectrometry method was established for the simultaneous determination of five organic amine substances in surface water,and the parameters of the headspace system were optimized.The linearity of 5 organic amine substances is good in the concentration range of 0.10~50.0mg·L-1,and the average recovery rate of the three concentration water samples is 88.0%~104.5%.The relative standard deviation of the 6 test results is less than 5%.This method is easy to operate,has a low detection limit,good accuracy and precision,and can meet the detection requirements of organic amine substances in surface water,groundwater and other water bodies.

headspacegas chromatography-mass spectrometrysurface waterorganic amines

袁艳阳

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河南省白龟山水库运行中心,河南 平顶山 467000

顶空 气相色谱质谱法 地表水 有机胺

2024

化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
年,卷(期):2024.38(5)