首页|H2S/CO2/O2环境下稠油热采生产井管柱腐蚀机理研究

H2S/CO2/O2环境下稠油热采生产井管柱腐蚀机理研究

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为了研究稠油热采生产井管柱腐蚀规律,采用室内挂片失重法实验对影响管柱腐蚀的主要因素进行评价,主要包括温度、H2S分压、CO2 分压及O2 分压,并通过分析腐蚀产物厘清腐蚀机理.实验结果表明,P110钢的腐蚀产物主要是FeCO3、FeS和Fe2O3,当温度低于 70℃时,腐蚀速率随着温度的升高而增大,70℃时达到最大值,随后开始减小;CO2、O2 分压增大,腐蚀速率增大,H2S分压增大,腐蚀速率先减小后增大.通过各因素对腐蚀速率的影响结果对比可知,O2 分压和温度对腐蚀速率的影响要高于H2S和CO2.腐蚀规律和机理对保障安全生产和提高管柱使用寿命具有重要意义.
Study on corrosion mechanism of heavy oil production well string in H2S/CO2/O2 environment
In order to study the corrosion law of heavy oil production well string,the main factors affecting the corrosion of pipe string were evaluated by weight loss test in laboratory,including temperature,H2S partial pressure,CO2 partial pressure and O2 partial pressure,the corrosion mechanism is clarified by analyzing the corrosion products.The results show that the main corrosion products of P110 steel are FeCO3,FeS and Fe2O3.When the temperature is less than 70℃,the corrosion rate increases with the increase of temperature,and reaches the maximum at 70℃,then begins to decrease.With the increase of CO2 and O2 partial pressure,the corrosion rate and H2S partial pressure increased,and the corrosion rate first decreased and then increased.The results show that the effect of oxygen partial pressure and temperature on corrosion rate is higher than that of H2S and CO2.The corrosion law and mechanism are of great significance for ensuring the safety of production and increasing the service life of pipe string.

three-phase mixed gascorrosion productscorrosion lawcorrosion mechanism

刘海彬、王宝峰、李洪毕、伊宏亮、赵长亮

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中国石油 辽河油田公司 采油工艺研究院,辽宁 盘锦 124010

三相混合气体 腐蚀产物 腐蚀规律 腐蚀机理

2024

化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
年,卷(期):2024.38(6)