首页|天然气输送管道用新型缓蚀剂的制备及性能研究

天然气输送管道用新型缓蚀剂的制备及性能研究

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为有效降低天然气输送管道的腐蚀速率,提高管道的运行效率,以植物油酸、多乙烯多胺和尿素为原料,通过两步法制备了一种天然气集输管道用新型缓蚀剂XHT-1.以合成产物产率为评价指标,对中间产物X和最终产物XHT-1的合成工艺进行了优化,并以缓蚀率为评价指标,对新型缓蚀剂XHT-1的腐蚀防护效果进行了评价.结果表明,当植物油酸和多乙烯多胺的单体摩尔比为1∶1.2、反应温度为130℃、反应时间为3h时,中间产物X的产率最大(90.6%);当中间产物X和尿素单体摩尔比为1∶0.8、反应温度为140℃、反应时间为4h时,新型缓蚀剂XHT-1的产率最大(98.2%).新型缓蚀剂XHT-1的浓度越大,缓蚀率相对就越大,当XHT-1的浓度为300mg·L-1时,缓蚀率可达到95.8%,缓蚀效果较好.研究结果认为,新型缓蚀剂XHT-1能够用于目标天然气输送管道的腐蚀防护中.
Study on preparation and performance of new corrosion inhibitors for natural gas pipeline
In order to effectively reduce the corrosion rate of natural gas transmission pipelines and improve their operational efficiency,a new corrosion inhibitor XHT-1 for natural gas gathering and transportation pipelines was prepared using vegetable oleic acid,polyethylene polyamines,and urea as raw materials through a two-step method.The synthesis process of intermediate product X and final product XHT-1 was optimized using synthetic product yield as the evaluation index,and the corrosion protection effect of the new corrosion inhibitor XHT-1 was evaluated using corrosion inhibition rate as the evaluation index.The results showed that the yield of intermediate product X was the highest(90.6%)when the monomer molar ratio of vegetable oleic acid and polyethylene polyamines was 1∶1.2,the reaction temperature was 130℃,and the reaction time was 3 hours;When the molar ratio of intermediate product X to urea monomer was 1:0.8,the reaction temperature was 140℃,and the reaction time was 4 hours,the yield of the new corrosion inhibitor XHT-1 was the highest(98.2%).The higher the concentration of the new corrosion inhibitor XHT-1,the higher the corrosion inhibition rate.When the concentration of XHT-1 was 300mg·L-1,the corrosion inhibition rate could reach 95.8%,indicating a good corrosion inhibition effect.The research results suggest that the new corrosion inhibitor XHT-1 can be used for corrosion protection of target natural gas transmission pipelines.

natural gas gathering and transportationpipeline corrosioncorrosion inhibitorssynthesis condi-tionsperformance evaluation

张闻、林俊、吴桐

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苏交科集团(江苏)安全科学研究院有限公司,江苏 南京 211112

国家石油天然气管网集团有限公司,北京 100000

天然气集输 管道腐蚀 缓蚀剂 合成条件 性能评价

中国石油科技创新基金

2022D-5009-1935

2024

化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
年,卷(期):2024.38(8)
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