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岩土工程用新型胶黏剂的制备及胶结土性能评价

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以聚酰胺固化剂650和硫脲为原料,制备了一种新型改性固化剂G-650,室内优化了其制备工艺条件,并将其与环氧树脂E-51、活性稀释剂XS-1和硅烷偶联剂KH550相结合,制备出了一种新型胶黏剂JZR-2,以抗压强度、抗折强度和相对渗透系数为评价指标,考察了 JZR-2对胶结土性能的影响.实验结果表明,新型改性固化剂G-650的最佳制备工艺条件为:硫脲用量为6%,反应温度为100℃,反应时间为60min.岩土样品中新型胶黏剂JZR-2的加量越大,胶结土试件的抗压强度和抗折强度就越大,而相对渗透系数就越小,推荐新型胶黏剂JZR-2的最佳用量为6%,此时胶结土试件的抗压强度可达10.36MPa,抗折强度可达3.85MPa,相对渗透系数可达0.68 × 10-7cm·s-1.研究结果认为,研制的新型胶黏剂JZR-2能够对岩土样品起到良好的胶结固化效果,可以大幅提升其强度和抗渗性能,能够满足岩土工程施工的需求.
Preparation of new adhesives for geotechnical engineering and evaluation of cemented soil properties
A new type of modified curing agent G-650 was prepared using polyamide curing agent 650 and thiourea as raw materials.The preparation process conditions were optimized indoors,and it was combined with epoxy resin E-51,active diluent XS-1,and silane coupling agent KH550 to prepare a new adhesive JZR-2.The impact of JZR-2 on the properties of cemented soil was investigated using compressive strength,flexural strength,and relative permeability coefficient as evaluation indicators.The experimental results show that the optimal preparation process conditions for the new modified curing agent G-650 are:the amount of thiourea is 6%,the reaction temperature is 100℃,and the reaction time is 60 minutes.The larger the dosage of the new adhesive JZR-2 in the rock and soil samples,the greater the compressive and flexural strength of the bonded soil specimens,and the smaller the relative permeability coefficient.It is recommended that the optimal dosage of the new adhesive JZR-2 is 6%.At this time,the compressive strength of the bonded soil specimens can reach 10.36 MPa,the flexural strength can reach 3.85 MPa,and the relative permeability coefficient can reach 0.68 ×10-7cm·s-1.The research results suggest that the developed new adhesive JZR-2 can achieve good bonding and solidification effects on geotechnical samples,significantly improve its strength and impermeability,and meet the requirements of geotechnical engineering construction.

adhesivegeotechnical engineeringcemented soilcompressive strengthflexural strength

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中冶地勘岩土工程有限责任公司,河北 廊坊 065201

胶黏剂 岩土工程 胶结土 抗压强度 抗折强度

中冶地勘岩土工程有限责任公司科研项目中冶地勘岩土工程有限责任公司科研项目

ZYDK-2022-35023702112022102101Z

2024

化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
年,卷(期):2024.38(8)
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