化学工程师2024,Vol.38Issue(12) :32-34,96.DOI:10.16247/j.cnki.23-1171/tq.20241232

双通道-气相色谱法快速测定土壤中石油烃(C10~C40)的含量

Rapid determination of petroleum hydrocarbons(C10~C40)content in soil by dual channel-GC

许峰
化学工程师2024,Vol.38Issue(12) :32-34,96.DOI:10.16247/j.cnki.23-1171/tq.20241232

双通道-气相色谱法快速测定土壤中石油烃(C10~C40)的含量

Rapid determination of petroleum hydrocarbons(C10~C40)content in soil by dual channel-GC

许峰1
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作者信息

  • 1. 江苏德普检测技术有限公司,江苏 苏州 215400
  • 折叠

摘要

建立了双通道-气相色谱法测定土壤中可萃取总石油烃(C10~C40)含量的方法,并对进样方式和色谱条件进行了优化.进样方式为双通道进样,采用TG5-SILMS(10m × 0.10mm × 0.10μm)分离.优化后的条件可以实现3min每个样品的快速测定.结果表明,可萃取石油烃(C10~C40)在9300mg·L-1浓度范围内具有良好的线性关系,相关系数为0.9999,检出限为4.70mg·kg-1,加标回收率在96.1%~110%之间,相对标准偏差为1.0%~3.4%.该方法操作简便、效率高,可满足土壤中石油烃检测的要求.

Abstract

A method is established for the determination of extractable total petroleum hydrocarbons(C10~C40)in soil by dual channel-gas chromatography,and the injection method and chromatographic conditions are optimized.The method is dual-channel injection and separated by TG5-SILMS(10m×0.10mm×0.10μm).The optimized conditions enable rapid determination of 3min per sample.The results showed that extractable total petroleum hydrocarbons(C10~C40)are good fitting relationship in the range of 9300mg·L-1,the correlation coefficient is 0.9999,the detection limit is 4.70mg·kg-1,the recovery is between 96.1%and 110%and the RSD is 1.0%~3.4%.The method has simple operation and high efficiency,which can meet the requirements of petroleum hydrocarbons detection in soil.

关键词

双通道/气相色谱/土壤/石油烃/C10~C40/加速溶剂萃取

Key words

dual-channel/GC/soil/TPH/C10~C40/ASE

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出版年

2024
化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
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