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燃煤电厂SCR脱硝的副产物对空预器的腐蚀性能研究

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为提高燃煤电厂SCR烟气脱硝系统的运行效率,降低脱硝副产物对空预器的腐蚀和堵塞的影响,在分析了目标燃煤电厂SCR脱硝副产物组成的基础之上,通过挂片失重腐蚀实验,重点考察了 NH4HSO4浓度、(NH4)2SO4浓度、腐蚀温度、腐蚀时间以及钢材类型对空预器腐蚀速率的影响.结果表明,目标燃煤电厂SCR脱硝副产物中NH4HSO4的含量最高,达到了 61.6%,(NH4)2SO4的含量也达到了 6.5%,硫酸盐的沉积容易对空预器产生严重的腐蚀危害.随着NH4HSO4和(NH4)2SO4浓度的逐渐增大以及腐蚀温度的逐渐升高,挂片的腐蚀速率逐渐增大;而随着腐蚀时间的逐渐延长,挂片的腐蚀速率则逐渐减小;另外,在相同的腐蚀实验条件下,耐候钢和不锈钢的腐蚀速率明显小于普通碳钢,其中316L不锈钢的腐蚀速率最小.研究结果认为,SCR脱硝副产物中NH4HSO4和(NH4)2SO4的存在会对空预器造成较为严重的腐蚀,应尽量降低脱硝副产物的生产量.
Research on the corrosion performance of SCR denitrification by-products on air preheaters in coal-fired power plants
In order to improve the operational efficiency of the SCR flue gas denitrification system in coal-fired power plants and reduce the corrosion and blockage effects of denitrification by-products on the air preheater,based on the analysis of the composition of SCR denitrification by-products in the target coal-fired power plant,a hanging plate weight loss corrosion experiment was conducted to focus on the effects of ammonium bisulfate concentration,ammonium sulfate concentration,corrosion temperature,corrosion time and steel type on the corrosion rate of the air preheater.The results show that the content of ammonium bisulfate in the by-products of SCR denitrification in the target coal-fired power plant is the highest,reaching 61.6%,and the content of ammonium sulfate also reaches 6.5%.The deposition of sulfate is prone to serious corrosion hazards on the air preheater.As the concentrations of ammonium bisulfate and ammonium sulfate gradually increase and the corrosion temperature gradually increases,the corrosion rate of the hanging pieces gradually increases;As the corrosion time gradually prolongs,the corrosion rate of the hanging pieces gradually decreases;In addition,under the same corrosion experimental conditions,the corrosion rate of weathering steel and stainless steel is significantly lower than that of ordinary carbon steel,with 316L stainless steel having the lowest corrosion rate.The research results suggest that the presence of ammonium bisulfate and ammonium sulfate in SCR denitrification by-products can cause severe corrosion to the air preheater,and the production of denitrification by-products should be minimized as much as possible.

coal-fired flue gasSCR denitrification by-productsammonium hydrogen sulfateair preheatercorrosion rate

陈杰、黄纪荣

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晋控电力蒲洲热电山西有限公司,山西永济 044500

山东创宇环保科技有限公司,山东济南 250000

燃煤烟气 SCR脱硝副产物 硫酸氢铵 空预器 腐蚀速率

2024

化学工程师
黑龙江省化工研究院

化学工程师

CSTPCD
影响因子:0.243
ISSN:1002-1124
年,卷(期):2024.38(12)