首页|铝箔表面改性方式对磷酸铁锂电池的影响

铝箔表面改性方式对磷酸铁锂电池的影响

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针对铝箔表面改性要求,对铝箔表面进行烘烤、电晕和涂碳处理,并制作 6 Ah软包磷酸铁锂电池.通过铝箔表面粗糙度、极片辊压附着力、电化学阻抗、存储、循环等测试,评估表面改性方式对铝箔、极片及电池性能的影响.结果表明,铝箔经过电晕处理后,表面粗糙度增加了 41%,极片附着力是原来的3.166倍.铝箔经电晕+涂碳处理后,电池阻抗少了一道铝箔与活性物质间的容抗弧,电池交流内阻降低至 5.59 mΩ,并提升了电池内阻一致性.铝箔经电晕和涂碳处理均能提升电池大电流放电性能,降低极化,提升放电平台,但相比电晕处理,涂碳处理效果更显著.同时,涂覆的碳对高温循环改善明显.
Effect of Al foil surface modification on properties of lithium iron phosphate batteries
According to the requirements of Al foil surface modification,the surface of Al foil is baked,corona and coated with carbon,and 6 Ah pouch type lithium iron batteries is made.The effects of surface modification methods on the performance of Al foil,electrode plate and battery are evaluated through the tests of Al foil surface roughness,electrode plate rolling adhesion,electrochemical impedance,storage,cycle,etc.The results show that the surface roughness of Al foil is increased by 41%after corona,and the adhesion of the electrode sheet is thus increased by 3.166 times as much as that of the base foil.After corona and carbon coating treatment,the impedance of the battery is reduced by one capacitance arc between the aluminum foil and the active substance.The alter-nating current resistance(ACR)of the battery is reduced to 5.59 mΩ,and the consistency of the internal resistance of the battery is improved.Corona and carbon coating can improve the high current discharge performance of the battery,reduce polarization,and improve the discharge platform,but carbon coating is more significant than corona.At the same time,the coated carbon significantly improves the high temperature cycle.

carbon-coated Al foilcoronabakesurface modificationlithium iron phosphatelithium ion battery

袁天明、李景康、阮超、孙晓辉

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杭州南都动力科技有限公司,浙江杭州 311103

涂碳铝箔 电晕 烘烤 表面改性 磷酸铁锂 锂离子电池

2023

能源化工
中国石化集团南京化学工业有限公司技术中心

能源化工

CSTPCD
影响因子:0.419
ISSN:2095-9834
年,卷(期):2023.44(6)
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