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复合相变材料的制备与评价

Preparation and evaluation of composite phase change material

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针对天然气水合物钻井过程中,钻井液易侵入地层改变水合物赋存的地层温度、压力及化学条件,进而导致井壁周围地层水合物分解及井壁失稳等问题.对南海海域水合物钻井过程中水合物分解导致井壁失稳的问题进行了分析及研究,采用智能控温的方法,通过蠕虫状石墨吸附改性正构烷烃制备了复合相变材料.结果表明,制备的复合相变材料相变潜热性能较好,相变温度在17~18℃时可控,粒径满足现场有效回收筛分粒度的基本要求,且与钻井液配伍性良好,适用于水合物储层钻井用水基钻井液体系.
In the process of gas hydrate drilling,the drilling fluid is easy to intrude into the formation and change the formation temperature,pressure and chemical conditions of the hydrate formation,leading to the decomposition of hydrates in the surrounding formation and instability of the wellbore.The problem of wellbore instability caused by hydrate decomposition during hydrate drilling in the South China Sea is analyzed and studied.A composite phase change material is prepared by using intelligent temperature control method,adsorbing and modifying n-alkanes with vermicular graphite.The results show that the prepared composite phase change material has good phase change latent heat performance,the phase change temperature is controllable in the range of 17-18℃,and the particle size can meet the basic requirements for effective recovery of screening particle size on site.It also has good compatibility with drilling fluid and is suitable for water-based drilling fluid system for hydrate reservoir drilling.

natural gas hydratetemperature control material,water-based drilling fluid

冯明、邱正松、康雨杰、赵欣、慕佳兴

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中海石油(中国)有限公司海南分公司,海南海口 570311

中海油海南能源有限公司,海南海口 570311

中国石油大学(华东)石油工程学院,山东青岛 266580

天然气水合物 控温材料 水基钻井液

中海油海南能源有限公司项目

CEL2021HNFN0029

2023

能源化工
中国石化集团南京化学工业有限公司技术中心

能源化工

CSTPCD
影响因子:0.419
ISSN:2095-9834
年,卷(期):2023.44(6)
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