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SCR烟气脱硝技术及脱硝效率影响因素研究

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SCR脱硝技术是燃煤电厂烟气脱硝最常用的技术之一,为了提高燃煤电厂烟气脱硝效率,以某燃煤电厂的SCR烟气脱硝系统为研究对象,考察了不同类型催化剂、氨氮比、反应温度、二氧化硫质量浓度、氧气体积分数以及含水量等因素对脱硝效率的影响.结果表明,镍基分子筛类催化剂Ni/ZSM的脱硝效果相对更好,脱硝效率明显高于其他催化剂;随着氨氮比的升高,脱硝效率逐渐增大,而随着反应温度的升高以及氧气体积分数的逐渐增大,脱硝效率呈现先升高后降低的趋势;随着二氧化硫质量浓度和含水量的逐渐增大,脱硝效率逐渐降低.当选择Ni/ZSM作为催化剂,控制氨氮比为1.0,反应温度为300℃,氧气体积分数为5%,二氧化硫质量浓度和含水量均为0时,燃煤烟气的SCR脱硝效率可以达到87.1%,脱硝效率较高.
Study on SCR flue gas denitrification technology and influencing factors of denitrification efficiency
SCR denitrification technology is one of the most commonly used technical measures for flue gas denitrification in coal-fired power plants.In order to improve the efficiency of flue gas denitrification in coal-fired power plants,the SCR flue gas denitrification system of a coal-fired power plant is studied to investigate the effects of different types of catalysts,ammonia nitrogen ratio,reaction temperature,sulfur dioxide mass concentration,oxygen volume fraction,and water content on denitrification efficiency.The results show that nickel based molecular sieve catalysts Ni/ZSM have relatively better denitrification efficiency,and the denitrification efficiency is significantly higher than other catalysts.As the ammonia nitrogen ratio increases,the denitrification efficiency gradually increases.However,with the increase of reaction temperature and oxygen volume fraction,the denitrification efficiency shows a trend of first increasing and then decreasing.As the water content and sulfur dioxide mass concentration gradually increase,the denitrification efficiency gradually decreases.When Ni/ZSM is selected as the catalyst,the ammonia nitrogen ratio is controlled to be 1.0,the reaction temperature is 300℃,the oxygen volume fraction is 5%,the sulfur dioxide mass concentration and water content are both 0,the SCR denitrification efficiency of coal-fired flue gas can reach 87.1%,and the denitrification efficiency is relatively high.

coal-fired power plantnitrogen oxidesSCR denitrification technologydenitrification efficiencyinfluencing factor

王雷、楼杰、周元祥

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国家能源集团江苏电力有限公司,江苏南京 210000

广东粤电靖海发电有限公司,广东揭阳 515223

西安热工研究院有限公司,陕西西安 710054

燃煤电厂 氮氧化物 SCR脱硝技术 脱硝效率 影响因素

2024

能源化工
中国石化集团南京化学工业有限公司技术中心

能源化工

CSTPCD
影响因子:0.419
ISSN:2095-9834
年,卷(期):2024.45(4)