首页|不同合成路线耦合制备沸石分子筛

不同合成路线耦合制备沸石分子筛

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沸石分子筛作为一种重要的多孔材料,由于其特殊的孔道结构、适宜的酸性以及较高的水热稳定性,在吸附、离子交换和催化等领域具有广泛的应用。沸石的经典水热合成路线存在沸石产率低、合成成本高、污染严重等问题。将各种经典沸石合成路线与近年来发展的非常规合成路线有机结合起来则是解决上述问题及实现合成沸石技术创新的一条重要途径。为此,本文首先介绍了近年来开发的一系列非常规沸石合成路线的原理及特点,其次简要介绍了沸石分子筛合成路线耦合的概念,然后重点阐述了微波合成、无溶剂合成、晶种导向法与其他路线耦合制备沸石分子筛的最新进展,最后对利用这些耦合路线合成沸石分子筛过程中存在的问题进行了分析与展望。
Coupling Different Synthesis Routes to Prepare Zeolite Molecular Sieves
Zeolites as one kind of important porous materials have a wide range of applications in the fields of adsorption,ion exchange,and catalysis due to their special pore structure,suitable acidity,and high hydrothermal stability.The classical hydrothermal route of synthesizing zeolites suffers from low zeolite yields,high synthesis costs,and serious pollution.Coupling the classical synthesis routes of zeolites with those recently developed new non-conventional routes is an important way to solve the above problems and achieve technological innovation in zeolite synthesis.To this end,this review firstly introduces the principles and characteristics of those non-conventional synthesis routes of zeolites,then briefly introduces the concepts of coupling synthesis routes of zeolites,and then focuses on the latest progress in the preparation of zeolites by microwave synthesis,solvent-free synthesis,and seed-directed synthesis coupled with other routes.Finally,the main problems existing in these coupling routes are analyzed and viewed.

microwave synthesisionothermal synthesissolvent-free synthesisseed-directed synthesiscoupling

赵新红、王浩、丁梦琦、李红伟、季东、李贵贤

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兰州理工大学石油化工学院 兰州 730050

甘肃省低碳能源化工重点实验室 兰州 730050

微波合成 离子热合成 无溶剂合成 晶种导向合成 耦合

国家自然科学基金甘肃省基础研究创新群体项目

2216802222JR5RA219

2024

化学进展
中国科学院基础科学局,化学部,文献情报中心 国家自然科学基金委员会化学科学部

化学进展

CSTPCD北大核心
影响因子:1.079
ISSN:1005-281X
年,卷(期):2024.36(4)