首页|氧化石墨烯的合成及其对龙胆紫染料废水的净化研究

氧化石墨烯的合成及其对龙胆紫染料废水的净化研究

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水体有机污染难以处理,制备吸附性能好、价廉易得、绿色高效的净化剂十分必要。采用改进的Hummers法制备GO,并研究了GO对染料污水的吸附性能。对比了该吸附剂对 6 种染料的吸附性能,得出对龙胆紫的吸附效果最好,故选取龙胆紫为研究对象。设计了单因素实验,系统研究了不同条件下氧化石墨烯对龙胆紫的吸附,并拟合吸附动力学和等温模型。探究发现,氧化石墨烯投加量 0。03 g,p H=9,吸附时间 30 min,转速 1 200 r/min,染料质量浓度为 50 mg/L时吸附最优,吸附率为 98。36%,吸附量 81。96 mg/g。等温模型符合 Langmuir吸附,动力学模型符合准二级动力学吸附。实验结果显示了氧化石墨烯对龙胆紫染料具有较强的吸附能力,有望在水体染料污染处理上发挥巨大作用。
Studies on Synthesis of Graphene Oxide for Purification of Crystal Violet Dye Wastewater
In order to find a kind of cheap and readily available material with good adsorption capacity and high efficiency for organic pollution treatment in water,the modified Hummers method was used in this experiment to prepare graphene oxide for dyeing wastewater treatment.A series of single-factor experiments were designed to systematically investigate the adsorption of graphene oxide on gentian violet under different conditions and to fit the adsorption kinetics and isothermal models.The results showed that the optimal adsorption conditions were p H=9,adsorbent dose 0.03 g,adsorption time 30 min,rotation speed 1 200 r/min,and an adsorption solution concentration 50 mg/L.Under optimal conditions,a maximum adsorption rate of 98.36%and an adsorption capacity up to 81.96 mg/g were achieved.The isotherm model is in line with Langmuir adsorption,and the kinetic model is in accordance with quasi second-order adsorption,which reflect the monolayer chemisorption mechanism.Graphene oxide showed strong selective adsorption ability for gentian violet and has high potential for decontamination of dye pollution in aquatic environment.

graphene oxidepurificationdye wastewatercrystal violet

田佳文、高海荣、高婕、荆岩岩、董远方、熊晨曦

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郑州师范学院化学化工学院,河南 郑州 450044

氧化石墨烯 净化 染料废水 龙胆紫

河南省高等学校重点科研项目河南省大学生创新项目郑州师范学院大学生创新项目

22B150023202312949008DCZ2022043

2024

化学世界
上海市化学化工学会

化学世界

影响因子:0.264
ISSN:0367-6358
年,卷(期):2024.65(2)
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