首页|悬浮聚合法制备多孔吡啶基阴离子交换树脂及其表征

悬浮聚合法制备多孔吡啶基阴离子交换树脂及其表征

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采用悬浮聚合法成功制备了多孔吡啶基弱碱性阴离子交换树脂(4VP-DVB),通过季铵化制备了强碱性阴离子交换树脂(4VP-DVBQ).对两种树脂采用粒径分析、扫描电子显微镜(SEM)、比表面积测试(BET)、傅立叶变换红外吸收光谱(FT IR)以及热重分析(TGA)等进行了表征,并对成本进行了评估.实验结果表明:两种树脂都具有规则的球形结构,粒径分布于40~130 μm,具备多孔性结构且平均孔径达15 nm;TGA结果表明,两种树脂有较好的热稳定性能,起始分解温度在200 ℃以上.
Preparation and Characterization of Porous Pyridyl Anion Exchange Resins by Suspension Polymerization
Porous pyridyl weakly basic anion exchange resin(4VP-DVB)was successfully prepared by suspension polymerization;then,strong basic anion exchange resin(4VP-DVBQ)was obtained by quaternization.Characterization such as particle size analysis,scanning electron microscope(SEM),adsorption isotherm technique(BET),Fourier transform infrared spectrometer(FT IR)and thermal gravimetric analysis(TGA)were performed for both resins,and the cost assessment was carried out.The results showed that both resins have a regular spherical structure with particle sizes ranging from 40 to 130μm and the porous structure with an average pore size of 15 nm;in addition.TGA can prove that both resins have good thermal stability,and the initial decomposition temperature is above 200 ℃.

suspension polymerizationpyridyl resinporous ion exchange resin

胡崇庆、韩刚、陈彦良

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上海市计量测试技术研究院化学与电流辐射计量技术研究所,上海 201203

悬浮聚合法 吡啶基树脂 多孔性离子交换树脂

上海市科委"扬帆计划"项目国家市场监督管理总局科技项目

19YF14416002022MK026

2024

化学世界
上海市化学化工学会

化学世界

影响因子:0.264
ISSN:0367-6358
年,卷(期):2024.65(3)
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