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水热法硼磷改性多孔炭及其电化学性能研究

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采用水热法硼磷改性椰壳多孔炭,并对其电化学性能进行研究.通过X射线衍射、红外光谱以及氮气吸脱附表征改性前后多孔炭的结构和性能;将多孔炭制作电化学电容器负极,通过恒流充放电、循环伏安以及交流阻抗测试分析其电化学性能.结果表明,水热法硼磷改性使多孔炭的微观结构及组成发生了一定变化,比电容等电化学性能有明显的提高.渗硼剂为氧化硼,渗硼量为15 (wt)%时,比电容达108 F/g,比原始样增长了92%;渗硼剂为硼酸,渗硼量为25 (wt)%时,比电容达到98 F/g,比原始样增长了83%.
Hydrothermal Co-doping of Boron and Phosphorus on Porous Carbons and their Electrochemical Properties
Hydrothermal co-doping of boron and phosphorus was used to modify the structure of coconut based porous carbon (PC).XRD,FT-IR and nitrogen adsorption were used to characterize the changes on PCs caused by doping.Galvanostatic charge-discharge,cyclic voltammetry and electrochemical impedance spectrometry analyses were used to investigate the electrochemical properties of PCs.The results showed that the structure and composition of PCs were changed and their electrochemical performances were greatly improved through hydrothermal co-doping of boron and phosphorus.The speufic capacitance of the PC modified with 15(wt)% boron oxide reached 108F/g,which is 92% higher than that of urtreated PC.While as for 25(wt)% boric acid modified PC,the highest spcific capacitance of 98F/g was obtained,83% higher than that of originel PC.

Porous carbonHydrothermal co-doping of boron and phosphorusElectrochemical property

李朋、谭明慧、刘军、吴文婷、郭宁、吴明铂

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中国石油大学(华东)重质油国家重点实验室 青岛266580

多孔炭 水热硼磷改性 电化学性能

国家自然科学基金中央高校基本科研业务费专项资金

20876176,51172285,5137227714CX02060A

2014

化学通报(印刷版)
中国科学院化学研究所 中国化学会

化学通报(印刷版)

CSTPCDCSCD
影响因子:0.547
ISSN:0441-3776
年,卷(期):2014.77(6)
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