碳纳米管对结晶紫的吸附研究
Adsorption of Crystal Violet on Carbon Nanotubes
王文香 1柏良久 1徐慧 1陈厚1
作者信息
- 1. 鲁东大学化学与材料科学学院 烟台264025
- 折叠
摘要
研究了碳纳米管对溶液中结晶紫的吸附性能,考察了溶液浓度、溶液pH、吸附时间和吸附温度等因素对吸附行为的影响,初步探讨了碳纳米管对结晶紫的吸附机理.结果表明,碳纳米管对结晶紫的吸附量随着溶液初始浓度的增大而升高;酸性条件有利于吸附的进行,最佳pH等于5;对结晶紫的吸附在3h达到平衡,吸附速率常数为779.76h-1;温度的变化对结晶紫的吸附量影响不大.通过Langmuir方程和Freundlich方程对吸附进行拟合,平衡吸附量Q.与平衡质量浓度C,之间的关系符合Freundlich等温吸附方程所描述的规律,说明吸附过程以物理吸附为主.
Abstract
Carbon nanotubes (CNTs) were employed to remove crystal violet (CV) from solution.Effects of concentration of CV and pH of solution, the adsorption time as well as the adsorption temperature on the adsorption behavior of CNTs were examined.The results showed that the adsorption capacity of CV on CNTs increased with increasing of the concentration of CV.CV can be adsorbed efficiently on CNTs in the pH range of 2 ～ 6 and the maximum of adsorption capacity is achieved at pH =5.The adsorption equilibrium time of CV on CNTs is 3h and the adsorption rate constant is 779.76 h-1 Little influence on the adsorption capacity was observed with the change of temperature.The linear correlation coefficients of Langmuir and Freundlich isotherms were determined and the resuhs revealed that Freundlich isotherm can fit the experimental results well, this means the mechanism of adsorption of CV on CNTs is mainly physical adsorption.
关键词
碳纳米管/结晶紫/吸附/机理/废水处理Key words
Carbon nanotubes (CNT)/Crystal violet/Adsorption/Mechanism/Wastewater treatment引用本文复制引用
出版年
2015
NETL
NSTL
维普
万方数据