插层结构过渡金属氢氧化物的制备及其能源应用研究进展
Research Progress in the Preparation and Energy Application of Intercalated Transition Metal Hydroxides
张秩远 1陈浩彤 1李妍 1于莉莉 1栗丽1
作者信息
- 1. 北京石油化工学院新材料与化工学院特种弹性体重点实验室 北京 102617
- 折叠
摘要
当今社会能源紧张和环境问题突出,开发能够代替化石燃料的可再生能源已引起研究者的广泛关注.层状材料在电化学储能和转换应用中具有巨大潜力,其中层状金属氢氧化物具有层板中的过渡金属呈单原子交替分散,种类、比例可调,层间阴离子种类可调等诸多特点,使其能够作为高性能二维纳米能源材料,在储能和电催化等领域具有广阔的应用前景.本文总结了过渡金属氢氧化物材料插层客体的不同类型和制备方法,深入讨论了过渡金属氢氧化物插层化合物在能源相关领域的应用,包括电催化、能源储存(电池、超级电容器)、光催化、传感器等.最后,对插层结构过渡金属氢氧化物相关的潜在挑战和前景进行了展望.
Abstract
The development of renewable energy sources that can replace-fossil fuels has attracted massive attention of researchers due to energy constraints and environmental problems in today's society.Layered materials have great potential in electrochemical energy storage and conversion applications,among which layered metal hydroxides possessing features such as alternating single-atom dispersion of transition metals in the layer plates,adjustable types and ratios,and adjustable types of interlayer anions,enable them to be used as high-performance two-dimensional materials with promising applications in energy storage and electrocatalysis.This article summarizes the different intercalation guests'types and preparation methods of transition metal hydroxide,and discuss the applications of intercalated transition metal hydroxide in energy fields,such as electrocatalysis,energy storage(batteries,supercapacitors),photocatalysis,sensors.Finally,potential challenges and prospects related to intercalated layered transition metal hydroxides materials are discussed.
关键词
层状金属氢氧化物/插层结构/电催化/超级电容器Key words
Layered metal hydroxide/Intercalation structure/Electrocatalysis/Supercapacitor引用本文复制引用
基金项目
国家自然科学基金项目(22105026)
北京市教委科技一般项目(KM202110017004)
北京石油化工学院URT项目(2022J00053)
北京石油化工学院URT项目(2023J00141)
出版年
2024