化学推进剂与高分子材料2024,Vol.22Issue(5) :44-49.DOI:10.16572/j.issn1672-2191.202409074

AlH3高能推进剂流变性能及可浇性判据

Rheological performance and castability criteria of AlH3 high energy propellant

高述虎 付爽 赵志坤 胡云逸 骆晓冬 周水平
化学推进剂与高分子材料2024,Vol.22Issue(5) :44-49.DOI:10.16572/j.issn1672-2191.202409074

AlH3高能推进剂流变性能及可浇性判据

Rheological performance and castability criteria of AlH3 high energy propellant

高述虎 1付爽 2赵志坤 2胡云逸 2骆晓冬 2周水平3
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作者信息

  • 1. 航天化学动力技术重点实验室,湖北航天化学技术研究所,湖北襄阳 441003
  • 2. 湖北航天化学技术研究所,湖北襄阳 441003
  • 3. 航天化学动力技术重点实验室,湖北航天化学技术研究所,湖北襄阳 441003;湖北航天化学技术研究所,湖北襄阳 441003
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摘要

利用真空喷淋浇注设备和流变学测试方法,研究了 AlH3高能推进剂药浆在适用期内的流变性能,探究药浆在不同浇注时间下的黏度、屈服值与可浇性之间的关系.实验结果表明,随着浇注时间的增加,药浆的黏度增大、剪切速率指数降低、假塑性增强.药浆的黏度随浇注时间的变化规律可以用经验公式ηt=η0+atb较为准确地描述.流变学本构方程Herschel-Bulkley可较为准确地描述药浆黏度、剪切速率、屈服值三者之间的关系.A1H3高能推进剂可浇性判据:药浆黏度在355.7 Pa.s以下、屈服值在82.3 Pa以下、单位质量流平面积在0.823 cm2/g以上可浇注;黏度在491.4 Pa·s以上、屈服值在117.6 Pa以上、单位质量流平面积在0.739 cm2/g以下无法浇注.

Abstract

The rheological performance of AlH3 high energy propellant slurry during the applicable period was investigated by using vacuum spray casting equipment and rheological testing methods,and the relationship among viscosity,yield value and castability of the slurry at different casting time was explored.The experimental results showed that the viscosity of the slurry increased,the shear rate index decreased,and the pseudo plasticity increased with the increase of casting time.The change rule of the slurry viscosity with the casting time could be described more accurately by the empirical formula ηt=η0+atb.The relationship among the slurry viscosity,shear rate and yield value could be more accurately described by the rheological constitutive equation Herschel-Bulkley.The criteria for castability of AlH3 high energy propellant were as follows:the slurry could be cast when the slurry viscosity was below 355.7 Pa·s,the yield value was below 82.3 Pa,and the leveling area per unit mass was above 0.823 cm2/g;the slurry could not be cast when the slurry viscosity was above 491.4 Pa·s,the yield value was above 117.6 Pa,and the leveling area per unit mass was below 0.739 cm2/g.

关键词

AlH3/固体推进剂/流变性能/屈服值/可浇性

Key words

AlH3/solid propellant/rheological performance/yield value/castability

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出版年

2024
化学推进剂与高分子材料
黎明化工研究院有限责任公司

化学推进剂与高分子材料

影响因子:0.289
ISSN:1672-2191
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