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白炭黑/炭黑在橡胶复合材料中的聚集行为

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分别以炭黑和白炭黑为主要补强填料制备了橡胶复合材料,采用橡胶加工分析仪的多种测试模式,对比研究复合材料在不同停放时间下的Payne效应,分析了不同停放时间下填料在聚集程度方面的差异,探究了炭黑、白炭黑抗聚集能力随停放时间的变化.分析了胶料在硫化温度热处理前后的Payne效应差异、硫化过程中各胶料的抗聚集能力.结合两类复合材料在不同温度下的流变测试结果,进一步分析了炭黑、白炭黑在不同热处理温度下的聚集情况.结果表明:炭黑填料分散略差但聚集程度不受高温影响;白炭黑填料分散较好且可以通过延长停放时间缓解高温导致的填料聚集加剧现象.
Aggregation behavior of silica/carbon black in rubber composites
In this work,the rubber composites were prepared using carbon black or silica as the main reinforcing fillers.Multiple testing modes of Rubber Processing Analyzers(RPA)were used to study the Payne effect of composites under different storage times.The differences in the aggregation degrees of fillers under different storage times were analyzed,and the changes in the anti-aggregation ability of carbon black or silica with storage time were explored.The Payne effect differences of rubber composites before and after vulcanization temperature heat treatment were studied,and the anti-aggregation ability of each rubber compounds during the vulcanization process was analyzed.Based on the rheological test results of two types of composites at different temperatures,the aggregation of carbon black and silica at different heat treatment temperatures was further analyzed.The results show that the dispersion of carbon black filler is slightly poor,but the degree of aggregation is not affected by high temperature.White carbon black filler has good dispersibility and can alleviate the intensification of filler aggregation caused by high temperature by extending the storage time.

silicafiller aggregationaggregation resistancedispersivitystorage time

刘豫皖、蔡金伶、樊斌斌

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风神轮胎股份有限公司,河南 焦作 454003

白炭黑 填料聚集 抗聚集能力 分散性 停放时间

New Biological Rubber Material Preparation Technology and Application Demonstration Program

SQ2017YFGX010138

2024

化学研究
河南大学

化学研究

CSTPCD
影响因子:0.471
ISSN:1008-1011
年,卷(期):2024.35(2)
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