首页|杜仲胶/MXene隔离网状结构复合薄膜的制备及性能研究

杜仲胶/MXene隔离网状结构复合薄膜的制备及性能研究

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近年来,电磁屏蔽问题日益严重,寻找开发高性能电磁屏蔽材料是现实的迫切需求。本文选用结晶性生物基杜仲胶(EUG)作为基体,具有独特的层状结构、丰富的表面基团及优异的导电性的MXene作为纳米填料,通过胶乳共混法制备了具有隔离网络结构的杜仲胶(EUG)/MXene复合薄膜。研究了MXene的用量和复合膜厚度对杜仲胶(EUG)/MXene复合薄膜的微观形貌与结构、结晶度、导电性能及电磁屏蔽性能的影响。研究表明,采用胶乳共混法制备的杜仲胶(EUG)/MXene隔离网状复合膜,随着MXene含量及复合薄膜厚度的增加,复合薄膜中丰富的EUG-MXene界面结构以及MXene表面的活性基团进一步促进了对电磁波的多重反射以及极化弛豫现象。在MXene体积含量为8。9%,膜厚度为400 μm时,复合膜的电磁屏蔽效果达到峰值47。9 dB,为杜仲胶电磁屏蔽复合材料进一步研究提供了基础。
Preparation and performance study of Eucommia ulmoides gum/MXene isolation network composite films
In recent years,the issue of electromagnetic shielding has become increasingly severe,and the search for high-performance electromagnetic shielding materials is a pressing practical need.In this study,crystalline bio-based Eucommia ulmoides gum(EUG)was chosen as the matrix,which possesses a unique layered structure,abundant surface functional groups,and excellent conductivity,while MXene was utilized as the nano-filler.Composite films of Eucommia ulmoides gum(EUG)/MXene with an isolation network structure were prepared via latex blending.The effects of MXene dosage and composite film thickness on the microstructure,crystallinity,conductivity and electromagnetic shielding performance of the Eucommia ulmoides gum(EUG)/MXene composite films were investigated.The results demonstrate that the Eucommia ulmoides gum(EUG)/MXene composite films prepared by latex blending exhibit enhanced electromagnetic wave reflection and polarization relaxation phenomena due to the enriched EUG-MXene interfacial structure and active functional groups on the MXene surface,with increasing MXene content and composite film thickness.At an MXene content of 8.9% and a thickness of 400 µm,the electromagnetic shielding effectiveness of the composite film reached a peak of 47.9 dB,laying the groundwork for further research on Eucommia ulmoides gum-based electromagnetic shielding composite materials.

electromagnetic shieldingEucommia ulmoides gumMXeneisolation structure

罗涛、韩利硕、康海澜、方庆红

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沈阳化工大学 材料科学与工程学院,辽宁 沈阳 110142

沈阳化工大学 辽宁省橡胶弹性体重点实验室,辽宁 沈阳 110142

电磁屏蔽 杜仲胶 MXene 隔离结构

2024

化学研究
河南大学

化学研究

CSTPCD
影响因子:0.471
ISSN:1008-1011
年,卷(期):2024.35(6)