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PEEK表面处理及其粘接性能研究

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聚醚醚酮(PEEK)具有机械性能优良和生物稳定性较好的优点,在航空航天、国防军工、口腔医学等方面有着较为广泛的应用前景.但是PEEK表面是疏水性的,且表面能较低,是一种难粘材料,阻碍了其应用.因此探究PEEK合适的表面处理方式对其应用至关重要.探究了不同目数砂纸打磨、不同电晕处理时间及砂纸打磨和电晕协同处理的方式对PEEK的微观形貌、水接触角、表面元素及粘接性能的影响.结果表明,在不同目数砂纸打磨处理中,80目砂纸打磨处理能够使PEEK表面产生较为明显的沟壑,增加胶接面积.电晕处理可以在PEEK表面引入含氧官能团,增加表面浸润性.随着电晕时间的增加,PEEK表面水接触角明显降低.先80目砂纸打磨再电晕30 s处理的PEEK表面水接触角最低,为17.10 °,且这种表面处理的PEEK胶接接头在25 ℃、120℃下粘接效果较好,胶接接头破坏形式均为PEEK材料破坏.
Study on the Surface Treatment and Bonding Properties of PEEK
Polyether ether ketone(PEEK)exhibits the advantages of excellent mechanical properties and good biostability and are widely used in aerospace,military industry and oral medicine.However,the surface of PEEK is hydrophobic and has a low surface energy,making it a difficult-to-bonding material,which hinders its application.Therefore,exploring suitable surface treatments for PEEK is crucial for its application.This experi-ment investigates the effect of different surface treatments such as sanding and corona coprocessing on the micro-morphology,water contact angle,surface elements and bonding performance of PEEK.The results show that for different grit sandpaper sanding treatment,80 grit sandpaper sanding produces more obvious grooves on the PEEK surface,increasing the bonding area.Corona treatment can introduce oxygen-containing functional groups on the PEEK surface,increasing the wettability.The water contact angle of the PEEK surface decreases significantly with increasing corona time.The contact angle of the PEEK after 80 grit sandpaper grinding and 30 s corona treatment is the lowest which is 17.10 °.The bonding perfor-mance of PEEK joints at 25 ℃,120 ℃ is better,and the damage form is the destruction of PEEK.

polyether ether ketonesurface treatmentbonding performanceepoxy adhesivecorona treatment

侯莉冉、赵立伟、王德志、肖万宝、李洪峰、宿凯、张杨

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黑龙江省科学院石油化学研究院,黑龙江哈尔滨 150040

聚醚醚酮 表面处理 粘接性能 环氧胶粘剂 电晕处理

2025

化学与粘合
黑龙江省化学学会 黑龙江省科学院石油化学研究院

化学与粘合

影响因子:0.386
ISSN:1001-0017
年,卷(期):2025.47(1)